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题名: Novel chiral phosphine-phosphoramidite ligands derived from 1-naphthylamine for highly efficient Rh-catalyzed asymmetric hydrogenation
作者: Yu, Sai-Bo1, 2;  Huang, Jia-Di1, 2;  Wang, Dao-Yong1, 2;  Hu, Xiang-Ping1;  Deng, Jun1, 2;  Duan, Zheng-Chao1, 2;  Zheng, Zhuo1
通讯作者: 郑卓
刊名: TETRAHEDRON-ASYMMETRY
发表日期: 2008-08-08
DOI: 10.1016/j.tetasy.2008.07.022
卷: 19, 期:15, 页:1862-1866
收录类别: SCI ;  IC
文章类型: Article
部门归属: 2
项目归属: 206
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic ;  Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Anew chiral phosphine-phosphoramidite ligand (S)-HY-Phos 1 has been prepared from 1-naphthylamine via a two-step transformation, and successfully applied in the Rh-catalyzed asymmetric hydrogenation of various functionalized olefins, including alpha-(acetamido)cinnamates, enamides and alpha-enol ester phosphonates, in which up to 98% ee, 99% ee and 99% ee were achieved, respectively. (C) 2008 Elsevier Ltd. All rights reserved
关键词[WOS]: ENOL ESTER PHOSPHONATES ;  N-H PROTON ;  ENANTIOSELECTIVE SYNTHESIS ;  ALPHA-HYDROXY ;  HYDROFORMYLATION ;  DERIVATIVES ;  INDOLPHOS ;  COMPLEXES ;  QUINAPHOS ;  KETONES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000259623600018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/100245
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Yu, Sai-Bo,Huang, Jia-Di,Wang, Dao-Yong,et al. Novel chiral phosphine-phosphoramidite ligands derived from 1-naphthylamine for highly efficient Rh-catalyzed asymmetric hydrogenation[J]. TETRAHEDRON-ASYMMETRY,2008,19(15):1862-1866.
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