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题名: Asymmetric catalysis with metal complexes in nanoreactors
作者: Yang, Qihua1;  Han, Difei1;  Yang, Hengquan1;  Li, Can1
通讯作者: 李灿
关键词: asymmetric catalysis ;  epoxidation ;  heterogeneous catalysis ;  nanoreactors ;  organosilicas
刊名: CHEMISTRY-AN ASIAN JOURNAL
发表日期: 2008
DOI: 10.1002/asia.200800110
卷: 3, 期:8-9, 页:1214-1229
收录类别: SCI
文章类型: Review
部门归属: 5
项目归属: 506,503
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Recently, the field of heterogeneous asymmetric catalysis, generally using chiral solid catalysts, has attracted much attention in the production of single enantiomers. Among versatile chiral solid catalysts, chiral metal complexes confined in nanoreactors often exhibit very unique enantioselectivity and catalytic activity compared to homogeneous catalysts. In this Focus Review, we summarize the recent advances in asymmetric reactions on chiral metal complexes confined in nanoreactors with an emphasis on the confinement effect and cooperative activation effect of the nanoreactor and new strategies for the preparation of chiral solid catalysts, such as the encapsulation of chiral metal complexes in the nanocages of mesoporous silica and incorporation of chiral ligands in the network of mesoporous organosilicas.
关键词[WOS]: PERIODIC MESOPOROUS ORGANOSILICAS ;  HETEROGENEOUS ENANTIOSELECTIVE REACTIONS ;  SUPPORTED CHIRAL CATALYSTS ;  MN(III) SALEN COMPLEXES ;  DIELS-ALDER REACTION ;  A-BOTTLE SYNTHESIS ;  UNFUNCTIONALIZED OLEFINS ;  NONFUNCTIONALIZED ALKENES ;  ORGANIC GROUPS ;  ZEOLITE-Y
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000259119400001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/100713
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China

Recommended Citation:
Yang, Qihua,Han, Difei,Yang, Hengquan,et al. Asymmetric catalysis with metal complexes in nanoreactors[J]. CHEMISTRY-AN ASIAN JOURNAL,2008,3(8-9):1214-1229.
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