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题名: The Franck-Condon region structure dynamics of p-nitrobenzoic acid from resonance Raman spectroscopy
作者: Pei, Kemei1, 2;  Ma, Yufang1, 2;  Zheng, Xuming1, 2;  Li, Haiyang3
通讯作者: Xuming Zheng
刊名: CHEMICAL PHYSICS LETTERS
发表日期: 2008-05-27
DOI: 10.1016/j.cplett.2008.04.048
卷: 457, 期:4-6, 页:323-328
收录类别: SCI
文章类型: Article
部门归属: 1
项目归属: 102
产权排名: 2;4
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: Resonance Raman spectra were obtained for p-nitrobenzoic acid using 266, 252.7, and 228.7 nm excitations. The spectra display overtones of the nominal NO(2) symmetric stretch mode upsilon(12) and the nominal NO2 antisymmetric stretch upsilon(8), and their combination bands with other four vibrational modes upsilon(19), upsilon(22), upsilon(17) and upsilon(10). A preliminary resonance Raman intensity analysis was done and the results for p-nitrobenzoic acid were compared with nitrobenzene, p-nitroaniline and p-nitrophenone. The results presented here indicate that the Franck-Condon region structure dynamics of nitroaromatic molecules will be dominated by nitro group when both -NO(2) and -COOH or -COCH(3) chromophores are coexisted in these kinds of molecules. (c) 2008 Elsevier B. V. All rights reserved.
关键词[WOS]: TIME PHOTODISSOCIATION DYNAMICS ;  A-BAND ABSORPTION ;  CYCLOHEXANE SOLUTION ;  MLCT TRANSITION ;  SPECTRA ;  FIELD ;  NM
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000255953800009
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/100739
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Peoples R China
2.Zhejiang Sci Tech Univ, State Key Lab ATMMT MOE, Hangzhou 310018, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Pei, Kemei,Ma, Yufang,Zheng, Xuming,et al. The Franck-Condon region structure dynamics of p-nitrobenzoic acid from resonance Raman spectroscopy[J]. CHEMICAL PHYSICS LETTERS,2008,457(4-6):323-328.
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