DICP OpenIR
One-pot synthesis and characterization of metal phosphide-doped carbon xerogels
Wang, Hui1,2; Shu, Yuying1; Wang, Aiqin1; Wang, Junhu1; Zheng, Mingyuan1; Wang, Xiaodong1; Zhang, Tao1; Shu YY(舒玉瑛); Zhang T(张涛); Shu YY(舒玉瑛); Zhang T(张涛)
刊名CARBON
2008-12-01
DOI10.1016/j.carbon.2008.08.021
46期:15页:2076-2082
收录类别SCI
文章类型Article
部门归属15
项目归属1501
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Materials Science
关键词[WOS]SURFACE CHARACTERISTICS ; HYDROTREATING ACTIVITY ; ORGANIC AEROGELS ; TRANSITION ; CATALYSTS ; DERIVATIVES ; MORPHOLOGY ; MOSSBAUER ; IRON ; CO
英文摘要Transition metal phosphide (Fe(2)P, Co(2)P and Ni(12)P(5))-doped carbon xerogels were synthesized by a one-pot pyrolysis of the sol-gel polymer of resorcinol and formaldehyde in the presence of metal nitrates and (NH(4))(2)HPO(4). Various techniques, including: X-ray diffraction, N(2) adsorption-desorption, scanning electron microscopy, transmission electron microscopy and Mossbauer spectra, were employed for characterizing the physico-chemical properties of this kind of phosphide-carbon composites. Comparing with the corresponding metal-doped carbon xerogels, metal phosphides can exert a different influence on the graphitization temperature, textural properties and surface morphology of the resultant carbon xerogels. investigations on the mechanism of iron phosphide formation indicated that CH(4), CO and C acted probably as reducing agents in the carbothermal reduction of metal phosphates. In addition, Mossbauer studies confirmed that this one-pot synthesis method was an excellent way for preparing high purity metal phosphide-doped carbon xerogels. (C) 2008 Elsevier Ltd. All rights reserved.
语种英语
原文出处查看原文
WOS记录号WOS:000261364500008
引用统计
被引频次:12[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/100831
专题中国科学院大连化学物理研究所
通讯作者Shu YY(舒玉瑛); Zhang T(张涛); Shu YY(舒玉瑛); Zhang T(张涛)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Wang, Hui,Shu, Yuying,Wang, Aiqin,et al. One-pot synthesis and characterization of metal phosphide-doped carbon xerogels[J]. CARBON,2008,46(15):2076-2082.
APA Wang, Hui.,Shu, Yuying.,Wang, Aiqin.,Wang, Junhu.,Zheng, Mingyuan.,...&张涛.(2008).One-pot synthesis and characterization of metal phosphide-doped carbon xerogels.CARBON,46(15),2076-2082.
MLA Wang, Hui,et al."One-pot synthesis and characterization of metal phosphide-doped carbon xerogels".CARBON 46.15(2008):2076-2082.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Wang, Hui]的文章
[Shu, Yuying]的文章
[Wang, Aiqin]的文章
百度学术
百度学术中相似的文章
[Wang, Hui]的文章
[Shu, Yuying]的文章
[Wang, Aiqin]的文章
必应学术
必应学术中相似的文章
[Wang, Hui]的文章
[Shu, Yuying]的文章
[Wang, Aiqin]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。