DICP OpenIR
Photodissociation dynamics of HN3 and DN3 at 157 nm
Yuan, Kaijun; Cheng, Yuan; Wang, Fengyan; Yang, Xueming; Yang XM(杨学明)
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY A
2008-06-19
Volume112Issue:24Pages:5332-5337
Indexed BySCI
SubtypeArticle
Department11
Funding Project1102
Contribution Rank1;1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS KeywordINTERNAL ENERGY-DISTRIBUTION ; ULTRAVIOLET PHOTODISSOCIATION ; NH ; PHOTOLYSIS ; STATE ; DISTRIBUTIONS ; EXCITATION ; SPECTRUM ; 1-DELTA ; CHANNEL
AbstractPhotodissociation dynamics of HN3 at 157.6 nm have been studied using the H-atom Rydberg tagging time-of-flight technique. Product translational energy distributions and angular distributions have been measured. From these distributions, three H-atom channels are observed. The vibrational structure in the fast-H channel could be assigned to a progression in the N-3 symmetric stretching mode (v(1)00), together with a progression of the symmetric stretching mode with one quantum of bending motion (v(1)10). The broad translational energy distribution of the slow-H channel is energetically consistent with the cyclic-N-3 formation process or a triple product dissociation channel. Photodissociation of DN3 was also investigated using the same technique. Isotope effect on the product translational energy distribution has been observed, in which the slow H-atom is clearly more pronounced.
Language英语
URL查看原文
WOS IDWOS:000256738800003
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/101111
Collection中国科学院大连化学物理研究所
Corresponding AuthorYang XM(杨学明)
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State key Lab Mol React Dynam, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Yuan, Kaijun,Cheng, Yuan,Wang, Fengyan,et al. Photodissociation dynamics of HN3 and DN3 at 157 nm[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2008,112(24):5332-5337.
APA Yuan, Kaijun,Cheng, Yuan,Wang, Fengyan,Yang, Xueming,&杨学明.(2008).Photodissociation dynamics of HN3 and DN3 at 157 nm.JOURNAL OF PHYSICAL CHEMISTRY A,112(24),5332-5337.
MLA Yuan, Kaijun,et al."Photodissociation dynamics of HN3 and DN3 at 157 nm".JOURNAL OF PHYSICAL CHEMISTRY A 112.24(2008):5332-5337.
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