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Exceptionally efficient unsymmetrical ruthenium(II) NNN complex catalysts bearing a pyridyl-based pyrazolyl-imidazolyl ligand for transfer hydrogenation of ketones
Zeng, Fanlong; Yu, Zhengkun; Yu ZK(余正坤)
Source PublicationORGANOMETALLICS
2008-07-14
DOI10.1021/om8002043
Volume27Issue:13Pages:2898-2901
Indexed BySCI ; IC ; CCR
SubtypeArticle
Department2
Funding Project203
Contribution Rank1;1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Inorganic & Nuclear ; Chemistry, Organic
WOS Research AreaChemistry
WOS KeywordASYMMETRIC TRANSFER HYDROGENATION ; CHIRAL LIGANDS ; POLAR BONDS ; REDUCTION ; HYDRIDE ; INTERMEDIATE ; PROPAN-2-OL ; MECHANISM ; PRECURSOR ; ALCOHOLS
AbstractRare ruthenium(II) complexes bearing a pyridyl-based pyrazolyl-imidazolyl ligand were synthesized and exhibited exceptionally high catalytic activity in the transfer hydrogenation of ketones in 2-propanol at 82 degrees C or room temperature, reaching 100% conversion of the substrates and final TOFs up to 7.2 x 10(5) h(-1) with 0.05 mol % catalyst at 82 degrees C and 55 800 h(-1) with 0.1 mol % catalyst at room temperature.
Language英语
URL查看原文
WOS IDWOS:000257448500005
Citation statistics
Cited Times:67[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/101161
Collection中国科学院大连化学物理研究所
Corresponding AuthorYu ZK(余正坤)
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Zeng, Fanlong,Yu, Zhengkun,Yu ZK. Exceptionally efficient unsymmetrical ruthenium(II) NNN complex catalysts bearing a pyridyl-based pyrazolyl-imidazolyl ligand for transfer hydrogenation of ketones[J]. ORGANOMETALLICS,2008,27(13):2898-2901.
APA Zeng, Fanlong,Yu, Zhengkun,&余正坤.(2008).Exceptionally efficient unsymmetrical ruthenium(II) NNN complex catalysts bearing a pyridyl-based pyrazolyl-imidazolyl ligand for transfer hydrogenation of ketones.ORGANOMETALLICS,27(13),2898-2901.
MLA Zeng, Fanlong,et al."Exceptionally efficient unsymmetrical ruthenium(II) NNN complex catalysts bearing a pyridyl-based pyrazolyl-imidazolyl ligand for transfer hydrogenation of ketones".ORGANOMETALLICS 27.13(2008):2898-2901.
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