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题名: Enantioselective synthesis of cyclic sulfamidates via Pd-catalyzed hydrogenation
作者: Wang, You-Qing;  Yu, Chang-Bin;  Wang, Da-Wei;  Wang, Xiao-Bing;  Zhou, Yong-Gui
通讯作者: 周永贵
刊名: ORGANIC LETTERS
发表日期: 2008-05-15
DOI: 10.1021/ol800591u
卷: 10, 期:10, 页:2071-2074
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 02
项目归属: 201
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Using Pd(CF(3)CO(2))(2)/(SS)-f-binaphane as the catalyst, an efficient enantioselective synthesis of cyclic sulfamidates was developed via asymmetric hydrogenation of the corresponding cyclic imines in 2,2,2-trifluoroethanol at room temperature with high enantioselectivities (up to 99% ee).
关键词[WOS]: ASYMMETRIC TRANSFER HYDROGENATION ;  N-ARYL IMINES ;  ORGANOCATALYTIC TRANSFER HYDROGENATION ;  GLYCOSYL AMINO-ACIDS ;  HETEROAROMATIC-COMPOUNDS ;  ORGANOMETALLIC REAGENTS ;  SULFAMATE ESTERS ;  HANTZSCH ESTERS ;  1,2,3-BENZOXATHIAZOLE 2,2-DIOXIDES ;  INTRAMOLECULAR AMIDATION
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000255694100049
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/101323
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Wang, You-Qing,Yu, Chang-Bin,Wang, Da-Wei,et al. Enantioselective synthesis of cyclic sulfamidates via Pd-catalyzed hydrogenation[J]. ORGANIC LETTERS,2008,10(10):2071-2074.
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