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题名: Hydroformylation of methyl-3-pentenoate over a phosphite ligand modified Rh/SiO2 catalyst
作者: Li, Xianming1, 3;  Ding, Yunjie1, 2;  Jiao, Guiping1, 3;  Li, Jingwei1, 3;  Yan, Li1;  Zhu, Hejun1
通讯作者: 丁云杰
关键词: Rh/SiO2 ;  phosphite ;  hydroformylation ;  internal olefins ;  linear aldehydes
刊名: JOURNAL OF NATURAL GAS CHEMISTRY
发表日期: 2008-12-01
卷: 17, 期:4, 页:351-354
收录类别: SCI
文章类型: Article
部门归属: 8
项目归属: 805
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Energy & Fuels ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Energy & Fuels ;  Engineering
英文摘要: A phosphite ligand modified Rb/SiO2 catalyst has been developed for hydroformylation of internal olefins to linear aldehydes, which showed high activity and regioselectivity and could be separated easily by filtration after reaction in an autoclave. Effects of reaction temperature and syngas pressure on the performances of the catalyst in the reaction were also investigated.
关键词[WOS]: SELECTIVE HYDROFORMYLATION ;  INTERNAL OLEFINS ;  RHODIUM ;  PROPYLENE ;  TRANS-4-OCTENE ;  ALDEHYDES ;  ALKENES ;  SYSTEMS ;  RH
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000262395200007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/101419
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Appl Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Li, Xianming,Ding, Yunjie,Jiao, Guiping,et al. Hydroformylation of methyl-3-pentenoate over a phosphite ligand modified Rh/SiO2 catalyst[J]. JOURNAL OF NATURAL GAS CHEMISTRY,2008,17(4):351-354.
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