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Low-temperature oxidation of CO catalysed by Co3O4 nanorods
Xie, Xiaowei1; Li, Yong1; Liu, Zhi-Quan2; Haruta, Masatake3,4; Shen, Wenjie1; Shen WJ(申文杰)
刊名NATURE
2009-04-09
DOI10.1038/nature07877
458期:7239页:746-749
收录类别SCI
文章类型Article
部门归属5
项目归属501
产权排名1;1
WOS标题词Science & Technology
类目[WOS]Multidisciplinary Sciences
研究领域[WOS]Science & Technology - Other Topics
关键词[WOS]CARBON-MONOXIDE ; OXIDE CATALYSTS ; SURFACE ; POWDERS ; OXYGEN ; WATER
英文摘要Low-temperature oxidation of CO, perhaps the most extensively studied reaction in the history of heterogeneous catalysis, is becoming increasingly important in the context of cleaning air and lowering automotive emissions(1,2). Hopcalite catalysts (mixtures of manganese and copper oxides) were originally developed for purifying air in submarines, but they are not especially active at ambient temperatures and are also deactivated by the presence of moisture(3,4). Noble metal catalysts, on the other hand, are water tolerant but usually require temperatures above 100 degrees C for efficient operation(5,6). Gold exhibits high activity at low temperatures and superior stability under moisture, but only when deposited in nanoparticulate form on base transition-metal oxides(7-9). The development of active and stable catalysts without noble metals for low-temperature CO oxidation under an ambient atmosphere remains a significant challenge. Here we report that tricobalt tetraoxide nanorods not only catalyse CO oxidation at temperatures as low as -77 degrees C but also remain stable in a moist stream of normal feed gas. High-resolution transmission electron microscopy demonstrates that the Co3O4 nanorods predominantly expose their {110} planes, favouring the presence of active Co3+ species at the surface. Kinetic analyses reveal that the turnover frequency associated with individual Co3+ sites on the nanorods is similar to that of the conventional nanoparticles of this material, indicating that the significantly higher reaction rate that we have obtained with a nanorod morphology is probably due to the surface richness of active Co3+ sites. These results show the importance of morphology control in the preparation of base transition-metal oxides as highly efficient oxidation catalysts.
语种英语
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WOS记录号WOS:000265193600037
引用统计
被引频次:1360[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/101621
专题中国科学院大连化学物理研究所
通讯作者Shen WJ(申文杰)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
3.Tokyo Metropolitan Univ, Grad Sch Urban Environm Sci, Dept Appl Chem, Tokyo 1920397, Japan
4.Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan
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Xie, Xiaowei,Li, Yong,Liu, Zhi-Quan,et al. Low-temperature oxidation of CO catalysed by Co3O4 nanorods[J]. NATURE,2009,458(7239):746-749.
APA Xie, Xiaowei,Li, Yong,Liu, Zhi-Quan,Haruta, Masatake,Shen, Wenjie,&申文杰.(2009).Low-temperature oxidation of CO catalysed by Co3O4 nanorods.NATURE,458(7239),746-749.
MLA Xie, Xiaowei,et al."Low-temperature oxidation of CO catalysed by Co3O4 nanorods".NATURE 458.7239(2009):746-749.
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