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Nanosized Co- and Ni-Catalyzed Ammonia Borane for Hydrogen Storage
He, Teng1; Xiong, Zhitao1; Wu, Guotao1; Chu, Hailiang1; Wu, Chengzhang1; Zhang, Tao1; Chen, Ping1,2,3; Chen P(陈萍)
刊名CHEMISTRY OF MATERIALS
2009-06-09
ISSN10.1021/cm900672h
DOI10.1021/cm900672h
21期:11页:2315-2318
收录类别SCI
文章类型Article
部门归属19,15
项目归属1901,1501
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Materials Science
关键词[WOS]THERMAL-DECOMPOSITION ; DEHYDROGENATION ; COBALT ; HYDRODESULFURIZATION ; AMIDOBORANES ; HYDROLYSIS ; GENERATION ; CHEMISTRY ; RELEASE ; LITHIUM
英文摘要A "co-precipitation" method was applied to introduce nanosized Co- and Ni-based catalysts to ammonia borane. It was observed that approximately 1 equiv. of hydrogen was evolved from the doped ammonia borane samples at a temperature as low as 59 degrees C. Moreover, the catalytic dehydrogenation did not present any induction period, undesirable byproduct borazine, or sample forming. Electron paramagnetic resonance (EPR) characterization revealed that Co in a partially reduced state is the active species in the catalytic dehydrogenation of ammonia borane.
语种英语
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WOS记录号WOS:000266708700020
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被引频次:129[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/101763
专题中国科学院大连化学物理研究所
通讯作者Chen P(陈萍)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore
3.Natl Univ Singapore, Dept Chem, Singapore 117542, Singapore
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GB/T 7714
He, Teng,Xiong, Zhitao,Wu, Guotao,et al. Nanosized Co- and Ni-Catalyzed Ammonia Borane for Hydrogen Storage[J]. CHEMISTRY OF MATERIALS,2009,21(11):2315-2318.
APA He, Teng.,Xiong, Zhitao.,Wu, Guotao.,Chu, Hailiang.,Wu, Chengzhang.,...&陈萍.(2009).Nanosized Co- and Ni-Catalyzed Ammonia Borane for Hydrogen Storage.CHEMISTRY OF MATERIALS,21(11),2315-2318.
MLA He, Teng,et al."Nanosized Co- and Ni-Catalyzed Ammonia Borane for Hydrogen Storage".CHEMISTRY OF MATERIALS 21.11(2009):2315-2318.
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