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Synthesis of sodium amidoborane (NaNH2BH3) for hydrogen production
Xiong, Zhitao1; Wu, Guotao3; Chua, Yong Shen2; Hu, Jianjiang1; He, Teng; Xu, Weiliang2; Chen, Ping1,2,3; Chen P(陈萍)
刊名ENERGY & ENVIRONMENTAL SCIENCE
2008
DOI10.1039/b805649h
1期:3页:360-363
收录类别SCI
文章类型Article
部门归属19
项目归属1901
产权排名3;2
WOS标题词Science & Technology ; Physical Sciences ; Technology ; Life Sciences & Biomedicine
类目[WOS]Chemistry, Multidisciplinary ; Energy & Fuels ; Engineering, Chemical ; Environmental Sciences
研究领域[WOS]Chemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology
关键词[WOS]AMMONIA-BORANE ; THERMAL-DECOMPOSITION ; STORAGE ; IMIDES
英文摘要The prospect of building a future energy system on hydrogen has stimulated much research effort in developing hydrogen storage technologies. One of the potential materials newly developed is sodium amidoborane (NaNH2BH3) which evolves similar to 7.5 wt% hydrogen at temperatures as low as 91 degrees C. In this paper, two methods of synthesizing pure NaNH2BH3 were reported. One method is by reacting NaH and ammonia borane in THF at low temperatures, and the other is by reacting NaNH2 and ammonia borane in THF at ambient temperature. Non-isothermal testing on the thermolysis of solid NaNH2BH3 showed that hydrogen evolution was composed of two exothermic steps. More than 1 equiv. H-2 was evolved rapidly at temperatures below 87 degrees C. After evolving 2 equiv. H-2, NaH was identified in solid products and coexisted with amorphous BN.
语种英语
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WOS记录号WOS:000263887900013
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被引频次:79[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/101801
专题中国科学院大连化学物理研究所
通讯作者Chen P(陈萍)
作者单位1.Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore
2.Natl Univ Singapore, Dept Chem, Singapore 117542, Singapore
3.Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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Xiong, Zhitao,Wu, Guotao,Chua, Yong Shen,et al. Synthesis of sodium amidoborane (NaNH2BH3) for hydrogen production[J]. ENERGY & ENVIRONMENTAL SCIENCE,2008,1(3):360-363.
APA Xiong, Zhitao.,Wu, Guotao.,Chua, Yong Shen.,Hu, Jianjiang.,He, Teng.,...&陈萍.(2008).Synthesis of sodium amidoborane (NaNH2BH3) for hydrogen production.ENERGY & ENVIRONMENTAL SCIENCE,1(3),360-363.
MLA Xiong, Zhitao,et al."Synthesis of sodium amidoborane (NaNH2BH3) for hydrogen production".ENERGY & ENVIRONMENTAL SCIENCE 1.3(2008):360-363.
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