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题名: In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane
作者: Ji Baofen1, 2;  Wang Jibo1;  Chu Wenling1;  Zhu Xuefeng1;  Yang Weishen1;  Lin Liwu1
通讯作者: 杨维慎
关键词: propane ;  propene ;  vanadium and magnesium oxide catalyst ;  oxygen activity ;  solid electrolyte potentiometry
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2009-05-01
卷: 30, 期:5, 页:375-377
收录类别: SCI
文章类型: Article
部门归属: 5
项目归属: 504
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: Periodic oscillations in the oxygen activity on a Mg2V2O7 catalyst during the oxidative dehydrogenation of propane were monitored in situ by solid electrolyte potentiometry. The results directly showed that the catalyst was first reduced and then oxidized. The rate-determining step was the adsorption and activation of propane on the Mg2V2O7 catalyst. Propane and oxygen were adsorbed on different sites of the Mg2V2O7 catalyst.
关键词[WOS]: MG-O CATALYSTS ;  SELECTIVE OXIDATION ;  PROPYLENE ;  MOLYBDATE ;  KINETICS ;  ACID
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000266790700001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/101821
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Ji Baofen,Wang Jibo,Chu Wenling,et al. In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane[J]. CHINESE JOURNAL OF CATALYSIS,2009,30(5):375-377.
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