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In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane
Ji Baofen1,2; Wang Jibo1; Chu Wenling1; Zhu Xuefeng1; Yang Weishen1; Lin Liwu1; Yang WS(杨维慎)
KeywordPropane Propene Vanadium And Magnesium Oxide Catalyst Oxygen Activity Solid Electrolyte Potentiometry
Source PublicationCHINESE JOURNAL OF CATALYSIS
2009-05-01
Volume30Issue:5Pages:375-377
Indexed BySCI
SubtypeArticle
Department5
Funding Project504
Contribution Rank1;1
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordMG-O CATALYSTS ; SELECTIVE OXIDATION ; PROPYLENE ; MOLYBDATE ; KINETICS ; ACID
AbstractPeriodic oscillations in the oxygen activity on a Mg2V2O7 catalyst during the oxidative dehydrogenation of propane were monitored in situ by solid electrolyte potentiometry. The results directly showed that the catalyst was first reduced and then oxidized. The rate-determining step was the adsorption and activation of propane on the Mg2V2O7 catalyst. Propane and oxygen were adsorbed on different sites of the Mg2V2O7 catalyst.
Language英语
URL查看原文
WOS IDWOS:000266790700001
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/101821
Collection中国科学院大连化学物理研究所
Corresponding AuthorYang WS(杨维慎)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Ji Baofen,Wang Jibo,Chu Wenling,et al. In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane[J]. CHINESE JOURNAL OF CATALYSIS,2009,30(5):375-377.
APA Ji Baofen.,Wang Jibo.,Chu Wenling.,Zhu Xuefeng.,Yang Weishen.,...&杨维慎.(2009).In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane.CHINESE JOURNAL OF CATALYSIS,30(5),375-377.
MLA Ji Baofen,et al."In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane".CHINESE JOURNAL OF CATALYSIS 30.5(2009):375-377.
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