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In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane
Ji Baofen1,2; Wang Jibo1; Chu Wenling1; Zhu Xuefeng1; Yang Weishen1; Lin Liwu1; Yang WS(杨维慎)
关键词Propane Propene Vanadium And Magnesium Oxide Catalyst Oxygen Activity Solid Electrolyte Potentiometry
刊名CHINESE JOURNAL OF CATALYSIS
2009-05-01
30期:5页:375-377
收录类别SCI
文章类型Article
部门归属5
项目归属504
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]MG-O CATALYSTS ; SELECTIVE OXIDATION ; PROPYLENE ; MOLYBDATE ; KINETICS ; ACID
英文摘要Periodic oscillations in the oxygen activity on a Mg2V2O7 catalyst during the oxidative dehydrogenation of propane were monitored in situ by solid electrolyte potentiometry. The results directly showed that the catalyst was first reduced and then oxidized. The rate-determining step was the adsorption and activation of propane on the Mg2V2O7 catalyst. Propane and oxygen were adsorbed on different sites of the Mg2V2O7 catalyst.
语种英语
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WOS记录号WOS:000266790700001
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/101821
专题中国科学院大连化学物理研究所
通讯作者Yang WS(杨维慎)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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Ji Baofen,Wang Jibo,Chu Wenling,et al. In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane[J]. CHINESE JOURNAL OF CATALYSIS,2009,30(5):375-377.
APA Ji Baofen.,Wang Jibo.,Chu Wenling.,Zhu Xuefeng.,Yang Weishen.,...&杨维慎.(2009).In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane.CHINESE JOURNAL OF CATALYSIS,30(5),375-377.
MLA Ji Baofen,et al."In Situ Monitoring of the Oxygen Activity on a Mg2V2O7 Catalyst during the Oxidative Dehydrogenation of Propane".CHINESE JOURNAL OF CATALYSIS 30.5(2009):375-377.
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