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题名: Phosphorus Ligand Modified Rh/SiO2 Catalyst for Hydroformylation of Methyl-3-pentenoate
作者: Li Xianming1, 2;  Ding Yunjie1;  Jiao Guiping2;  Li Jingwei2;  Yan Li;  Zhu Hejun
通讯作者: 丁云杰
关键词: hydroformylation ;  heterogeneous catalyst ;  internal olefin ;  electronic effect ;  steric effect
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2008-12-01
卷: 29, 期:12, 页:1193-1195
收录类别: SCI
文章类型: Article
部门归属: 8
项目归属: 805
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: A phosphorus ligand-modified Rh/SiO2 catalyst (L-Rh/SiO2) has been developed for hydroformylaiion of internal olefins to linear aldehydes. This catalyst has high activity and regioselectivity and can be separated easily by filtration after reaction in an autoclave. Moreover, the electronic and steric effects of phosphorus ligands on the catalytic performance of the L-Rh/SiO2 catalyst have been investigated by using various monodentate and chelating diphosphorus ligands.
关键词[WOS]: DIPHOSPHINE LIGANDS ;  INTERNAL OLEFINS ;  BITE ANGLE ;  RH
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000262385100001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/101951
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Li Xianming,Ding Yunjie,Jiao Guiping,et al. Phosphorus Ligand Modified Rh/SiO2 Catalyst for Hydroformylation of Methyl-3-pentenoate[J]. CHINESE JOURNAL OF CATALYSIS,2008,29(12):1193-1195.
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