中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: A new concept of tethered ligand-modified Rh/SiO2 catalyst for hydroformylation with high stability
作者: Li, Xianming1, 3;  Ding, Yunjie1, 2;  Jiao, Guiping1, 3;  Li, Jingwei1, 3;  Lin, Ronghe1, 3;  Gong, Leifeng1, 3;  Yan, Li1;  Zhu, Hejun1
通讯作者: 丁云杰
关键词: Tethered ligand ;  Rh/SiO2 catalyst ;  Hydroformylation
刊名: APPLIED CATALYSIS A-GENERAL
发表日期: 2009-02-01
DOI: 10.1016/j.apcata.2008.10.052
卷: 353, 期:2, 页:266-270
收录类别: SCI
文章类型: Article
部门归属: 8
项目归属: 805
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences ;  Life Sciences & Biomedicine
类目[WOS]: Chemistry, Physical ;  Environmental Sciences
研究领域[WOS]: Chemistry ;  Environmental Sciences & Ecology
英文摘要: A tethered ligand-modified Rh/SiO2 Catalyst Was developed for hydroformylation with high stability. The catalyst was prepared by fastening both organic ligand and metal directly on the surface of support to avoid leaching, while at the same time the active species were formed in situ by coordination of the flexible ligand to the metal on the surface Of SiO2. The immobilization of ligand on SiO2 and the interaction between ligand and metal were investigated by means of TG, solid-state NMR and FTIR. Hydroformylation of ethylene was selected as a probe reaction to evaluate the immobilization and coordination of ligand to the nano-metal particles. High activity and excellent stability were observed during a 1000-h run. (C) 2008 Elsevier B.V. All rights reserved.
关键词[WOS]: TRANSITION-METAL-COMPLEXES ;  HETEROGENEOUS CATALYSTS ;  PPH3 LIGAND ;  SILICA ;  RHODIUM
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000263187800015
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/101961
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Appl Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Li, Xianming,Ding, Yunjie,Jiao, Guiping,et al. A new concept of tethered ligand-modified Rh/SiO2 catalyst for hydroformylation with high stability[J]. APPLIED CATALYSIS A-GENERAL,2009,353(2):266-270.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Li, Xianming]'s Articles
 [Ding, Yunjie]'s Articles
 [Jiao, Guiping]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Li, Xianming]‘s Articles
 [Ding, Yunjie]‘s Articles
 [Jiao, Guiping]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace