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题名: Feasibility Study of Hydrogen Generation from the Milled Al-Based Materials for Micro Fuel Cell Applications
作者: Fan, Mei-qiang1, 2;  Sun, Li-xian1;  Xu, Fen1
通讯作者: 范美强
刊名: ENERGY & FUELS
发表日期: 2009-09-01
DOI: 10.1021/ef9004169
卷: 23, 页:4562-4566
收录类别: SCI
文章类型: Article
部门归属: 15
项目归属: 1504
产权排名: 2;2
WOS标题词: Science & Technology ;  Technology
类目[WOS]: Energy & Fuels ;  Engineering, Chemical
研究领域[WOS]: Energy & Fuels ;  Engineering
英文摘要: Hydrogen generation from hydrolysis of the milled At materials in watar at room temperature Is investigated, The hydrolysis mechanism is based oil the work of the microgalvanic cell, where AlOOH (Bohmite) and hydrogen are produced via consumption of Al and water. From the hydrolysis results, the Al-Bi-based materials have better hydrolysis properties than those of the Al-Sn-based materials. Approximately 1000 mL of H, per gram of the Al-Bi-based materials can be generated, and the hydrogen generation rate can be achieved at 160 mL/g/min in the first five minutes of hydrolysis. The high reactivity of the Al-Bi materials conic from the additives (Zn, hydrides, and salts) and can be achieved in 5 h of milling. Meanwhile, the feasibility of the CO(2)-free hydrogen from At alloys for fuel cell applications is confirmed in pur experiments, and the hydrogen generation can be controlled by feeding the water flow into the At alloys.
关键词[WOS]: SODIUM-BOROHYDRIDE SOLUTION ;  CATALYST ;  HYDROLYSIS ;  WATER ;  METAL
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000270671500045
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/101987
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.China Jiliang Univ, Dept Mat Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China

Recommended Citation:
Fan, Mei-qiang,Sun, Li-xian,Xu, Fen. Feasibility Study of Hydrogen Generation from the Milled Al-Based Materials for Micro Fuel Cell Applications[J]. ENERGY & FUELS,2009,23:4562-4566.
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