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题名: Ruthenium(II) complex catalysts bearing a pyridyl-supported pyrazolyl-imine ligand for transfer hydrogenation of ketones
作者: Zhao, Miao1, 2;  Yu, Zhengkun1;  Yan, Shenggang3;  Li, Yang2
通讯作者: 余正坤
关键词: Arylimino ;  Pyrazolylpyridine ;  Ruthenium ;  Transfer hydrogenation ;  Ketones
刊名: JOURNAL OF ORGANOMETALLIC CHEMISTRY
发表日期: 2009-09-01
DOI: 10.1016/j.jorganchem.2009.05.028
卷: 694, 期:19, 页:3068-3075
收录类别: SCI ;  IC
文章类型: Article
部门归属: 2
项目归属: 203
产权排名: 2;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A new class of hemilabile unsymmetrical 2-(1-arylimino)-6-(pyzazol-1-yl)pyridine ligands and their ruthenium(II) and nickel(II) NNN complexes were synthesized. The Ru(II) complex catalysts have been fully characterized and exhibited good to excellent catalytic activity in the transfer hydrogenation (TH) of ketones in refluxing 2-propanol. These results have demonstrated rare examples of active ruthenium(II) NNN complex catalysts that do not feature a N-H functionality for TH of ketones. (C) 2009 Elsevier B. V. All rights reserved.
关键词[WOS]: ASYMMETRIC TRANSFER HYDROGENATION ;  ENANTIOSELECTIVE TRANSFER HYDROGENATION ;  ETHYLENE OLIGOMERIZATION ;  IMIDAZOLYL LIGAND ;  POLYMERIZATION ;  FUNCTIONALITY ;  REDUCTION ;  HYDRIDE ;  BOND
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000268799500004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/102307
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Dalian Univ Technol, Dept Polymer Mat, Coll Chem Engn, Dalian 116012, Liaoning, Peoples R China
3.Dalian Maritime Univ, Electromech & Mat Engn Coll, Dalian 116026, Liaoning, Peoples R China

Recommended Citation:
Zhao, Miao,Yu, Zhengkun,Yan, Shenggang,et al. Ruthenium(II) complex catalysts bearing a pyridyl-supported pyrazolyl-imine ligand for transfer hydrogenation of ketones[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2009,694(19):3068-3075.
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