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Room-temperature Ru(II)-catalyzed transfer hydrogenation of ketones and aldehydes in air
Zhao, Miao1,2; Yu, Zhengkun1; Yan, Shenggang3; Li, Yang2; Yu ZK(余正坤)
Source PublicationTETRAHEDRON LETTERS
2009-08-12
ISSN0040-4039
DOI10.1016/j.tetlet.2009.05.100
Volume50Issue:32Pages:4624-4628
Indexed BySCI ; CCR
SubtypeArticle
Department2
Funding Project203
Contribution Rank2;1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordASYMMETRIC TRANSFER-HYDROGENATION ; ENANTIOSELECTIVE TRANSFER HYDROGENATION ; CHEMOSELECTIVE TRANSFER HYDROGENATION ; TETHERED RUTHENIUM(II) CATALYST ; PYRAZOLYL-IMIDAZOLYL LIGAND ; AROMATIC KETONES ; PNNP LIGAND ; COMPLEXES ; WATER ; BEARING
AbstractTransfer hydrogenation (TH) of ketones and aldehydes was efficiently carried out in 2-propanol at room temperature by means of a ruthenium(II) complex catalyst bearing a 2-(benzoimidazol-2-yl)-6-(pyrazol-1-yl)pyridine ligand. TH of the ketone substrates proceeded in air, reaching final TOFs of up to 59,400 h(-1), and the reduction of aldehydes proceeded under a nitrogen atmosphere to achieve final TOFs of up to 5940 h(-1). (C) 2009 Elsevier Ltd. All rights reserved.
Language英语
URL查看原文
WOS IDWOS:000267901800014
Citation statistics
Cited Times:43[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/102311
Collection中国科学院大连化学物理研究所
Corresponding AuthorYu ZK(余正坤)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Dalian Univ Technol, Coll Chem Engn, Dept Polymer Mat, Dalian 116012, Liaoning, Peoples R China
3.Dalian Maritime Univ, Electromech & Mat Engn Coll, Dalian 116026, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Miao,Yu, Zhengkun,Yan, Shenggang,et al. Room-temperature Ru(II)-catalyzed transfer hydrogenation of ketones and aldehydes in air[J]. TETRAHEDRON LETTERS,2009,50(32):4624-4628.
APA Zhao, Miao,Yu, Zhengkun,Yan, Shenggang,Li, Yang,&余正坤.(2009).Room-temperature Ru(II)-catalyzed transfer hydrogenation of ketones and aldehydes in air.TETRAHEDRON LETTERS,50(32),4624-4628.
MLA Zhao, Miao,et al."Room-temperature Ru(II)-catalyzed transfer hydrogenation of ketones and aldehydes in air".TETRAHEDRON LETTERS 50.32(2009):4624-4628.
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