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Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-2-phosphonomethylpropenoates by a New Class of Chiral Ferrocenyl Diphosphine Ligands
Wang, Dao-Yong1,2; Hu, Xiang-Ping1; Hou, Chuan-Jin1; Deng, Jun1,2; Yu, Sai-Bo1,2; Duan, Zheng-Chao1,2; Huang, Jia-Di1,2; Zheng, Zhuo1; Zheng Z(郑卓)
刊名ORGANIC LETTERS
2009-08-06
DOI10.1021/ol9012469
11期:15页:3226-3229
收录类别SCI ; IC ; CCR
文章类型Article
部门归属2
项目归属206
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]PHOSPHINE-PHOSPHORAMIDITE LIGANDS ; PHOSPHONIC ACID-DERIVATIVES ; GLUTAMYL-GAMMA-GLUTAMATE ; ASYMMETRIC HYDROGENATION ; POTENT INHIBITORS ; METAL-COMPLEXES ; STEREOSELECTIVE-SYNTHESIS ; SELECTIVE INHIBITORS ; SYNTHETASE ; LEADS
英文摘要A new class of chiral ferrocenyl diphosphine ligands with an imidazole ring, (R(c), S(Fc))-ImiFerroPhos, has been prepared from acylferrocenes through a five-step transformation and successfully applied in the Rh-catalyzed asymmetric hydrogenation of various 3-aryl-substituted 2-phosphonomethylpropenoates, in which a series of chiral 3-phosphono-2-arylmethylpropanoic acid derivatives were achieved in ee values of up to 98%.
语种英语
原文出处查看原文
WOS记录号WOS:000268479900017
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/102351
专题中国科学院大连化学物理研究所
通讯作者Zheng Z(郑卓)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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GB/T 7714
Wang, Dao-Yong,Hu, Xiang-Ping,Hou, Chuan-Jin,et al. Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-2-phosphonomethylpropenoates by a New Class of Chiral Ferrocenyl Diphosphine Ligands[J]. ORGANIC LETTERS,2009,11(15):3226-3229.
APA Wang, Dao-Yong.,Hu, Xiang-Ping.,Hou, Chuan-Jin.,Deng, Jun.,Yu, Sai-Bo.,...&郑卓.(2009).Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-2-phosphonomethylpropenoates by a New Class of Chiral Ferrocenyl Diphosphine Ligands.ORGANIC LETTERS,11(15),3226-3229.
MLA Wang, Dao-Yong,et al."Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-2-phosphonomethylpropenoates by a New Class of Chiral Ferrocenyl Diphosphine Ligands".ORGANIC LETTERS 11.15(2009):3226-3229.
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