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题名: Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-2-phosphonomethylpropenoates by a New Class of Chiral Ferrocenyl Diphosphine Ligands
作者: Wang, Dao-Yong1, 2;  Hu, Xiang-Ping1;  Hou, Chuan-Jin1;  Deng, Jun1, 2;  Yu, Sai-Bo1, 2;  Duan, Zheng-Chao1, 2;  Huang, Jia-Di1, 2;  Zheng, Zhuo1
通讯作者: 郑卓
刊名: ORGANIC LETTERS
发表日期: 2009-08-06
DOI: 10.1021/ol9012469
卷: 11, 期:15, 页:3226-3229
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 206
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A new class of chiral ferrocenyl diphosphine ligands with an imidazole ring, (R(c), S(Fc))-ImiFerroPhos, has been prepared from acylferrocenes through a five-step transformation and successfully applied in the Rh-catalyzed asymmetric hydrogenation of various 3-aryl-substituted 2-phosphonomethylpropenoates, in which a series of chiral 3-phosphono-2-arylmethylpropanoic acid derivatives were achieved in ee values of up to 98%.
关键词[WOS]: PHOSPHINE-PHOSPHORAMIDITE LIGANDS ;  PHOSPHONIC ACID-DERIVATIVES ;  GLUTAMYL-GAMMA-GLUTAMATE ;  ASYMMETRIC HYDROGENATION ;  POTENT INHIBITORS ;  METAL-COMPLEXES ;  STEREOSELECTIVE-SYNTHESIS ;  SELECTIVE INHIBITORS ;  SYNTHETASE ;  LEADS
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000268479900017
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/102351
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Wang, Dao-Yong,Hu, Xiang-Ping,Hou, Chuan-Jin,et al. Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-2-phosphonomethylpropenoates by a New Class of Chiral Ferrocenyl Diphosphine Ligands[J]. ORGANIC LETTERS,2009,11(15):3226-3229.
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