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Asymmetric transfer hydrogenation using recoverable ruthenium catalyst immobilized into magnetic mesoporous silica
Li, Jun; Zhang, Yanmei; Han, Difei; Gao, Qiang; Li, Can; Li C(李灿)
KeywordAsymmetric Transfer Hydrogenation Magnetic Nanoparticles Mesoporous Silica Imine Ketone
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
2009-02-02
DOI10.1016/j.molcata.2008.09.027
Volume298Issue:1-2Pages:31-35
Indexed BySCI
SubtypeArticle
Department5
Funding Project503
Contribution Rank1;1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordRU-TSDPEN CATALYSTS ; CHIRAL CATALYSTS ; AROMATIC KETONES ; MESOCELLULAR FOAM ; NANOPARTICLES ; WATER ; EFFICIENT ; FUNCTIONALIZATION ; ALCOHOLS ; IMINES
AbstractRu-TsDPEN (TsDPEN=N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine) derived catalyst was firstly immobilized in the magnetic siliceous mesocellular foam material. This heterogeneous catalyst afforded high catalytic activities and ee values in the asymmetric transfer hydrogenation of imine in HCOOH-Et(3)N system and aromatic ketones in aqueous HCOONa. Furthermore, this heterogeneous catalyst showed an excellent durability and can be reused conveniently by external magnet for at least nine times without noticeable loss of ee values. (C) 2008 Published by Elsevier B.V.
Language英语
URL查看原文
WOS IDWOS:000262882100006
Citation statistics
Cited Times:76[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/102529
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi C(李灿)
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Li, Jun,Zhang, Yanmei,Han, Difei,et al. Asymmetric transfer hydrogenation using recoverable ruthenium catalyst immobilized into magnetic mesoporous silica[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2009,298(1-2):31-35.
APA Li, Jun,Zhang, Yanmei,Han, Difei,Gao, Qiang,Li, Can,&李灿.(2009).Asymmetric transfer hydrogenation using recoverable ruthenium catalyst immobilized into magnetic mesoporous silica.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,298(1-2),31-35.
MLA Li, Jun,et al."Asymmetric transfer hydrogenation using recoverable ruthenium catalyst immobilized into magnetic mesoporous silica".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 298.1-2(2009):31-35.
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