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Asymmetric transfer hydrogenation using recoverable ruthenium catalyst immobilized into magnetic mesoporous silica
Li, Jun; Zhang, Yanmei; Han, Difei; Gao, Qiang; Li, Can; Li C(李灿)
关键词Asymmetric Transfer Hydrogenation Magnetic Nanoparticles Mesoporous Silica Imine Ketone
刊名JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
2009-02-02
DOI10.1016/j.molcata.2008.09.027
298期:1-2页:31-35
收录类别SCI
文章类型Article
部门归属5
项目归属503
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]RU-TSDPEN CATALYSTS ; CHIRAL CATALYSTS ; AROMATIC KETONES ; MESOCELLULAR FOAM ; NANOPARTICLES ; WATER ; EFFICIENT ; FUNCTIONALIZATION ; ALCOHOLS ; IMINES
英文摘要Ru-TsDPEN (TsDPEN=N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine) derived catalyst was firstly immobilized in the magnetic siliceous mesocellular foam material. This heterogeneous catalyst afforded high catalytic activities and ee values in the asymmetric transfer hydrogenation of imine in HCOOH-Et(3)N system and aromatic ketones in aqueous HCOONa. Furthermore, this heterogeneous catalyst showed an excellent durability and can be reused conveniently by external magnet for at least nine times without noticeable loss of ee values. (C) 2008 Published by Elsevier B.V.
语种英语
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WOS记录号WOS:000262882100006
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/102529
专题中国科学院大连化学物理研究所
通讯作者Li C(李灿)
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Li, Jun,Zhang, Yanmei,Han, Difei,et al. Asymmetric transfer hydrogenation using recoverable ruthenium catalyst immobilized into magnetic mesoporous silica[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2009,298(1-2):31-35.
APA Li, Jun,Zhang, Yanmei,Han, Difei,Gao, Qiang,Li, Can,&李灿.(2009).Asymmetric transfer hydrogenation using recoverable ruthenium catalyst immobilized into magnetic mesoporous silica.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,298(1-2),31-35.
MLA Li, Jun,et al."Asymmetric transfer hydrogenation using recoverable ruthenium catalyst immobilized into magnetic mesoporous silica".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 298.1-2(2009):31-35.
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