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题名: Wet air co-oxidation of decabromodiphenyl ether (BDE209) and tetrahydrofuran
作者: Zhao, Hongxia1, 2;  Zhang, Feifang1;  Qu, Baocheng2;  Xue, Xingya1;  Liang, Xinmiao1
通讯作者: 梁鑫淼
关键词: Co-oxidation ;  BDE209 ;  THF ;  Promotion effect ;  Free radical
刊名: JOURNAL OF HAZARDOUS MATERIALS
发表日期: 2009-09-30
DOI: 10.1016/j.jhazmat.2009.03.089
卷: 169, 期:1-3, 页:1146-1149
收录类别: SCI
文章类型: Article
部门归属: 18
项目归属: 1803
产权排名: 1;1
WOS标题词: Science & Technology ;  Technology ;  Life Sciences & Biomedicine
类目[WOS]: Engineering, Environmental ;  Engineering, Civil ;  Environmental Sciences
研究领域[WOS]: Engineering ;  Environmental Sciences & Ecology
英文摘要: The wet air co-oxidation (WACO) of a major commercial polybrominated diphenyl ether flame retardant congener, decabromodiphenyl ether (BDE209), was investigated using tetrahydrofuran (THF) as an initiator in a stainless autoclave at temperature range of 120-170 degrees C and 0.5 MPa oxygen pressure. Compared to the single oxidation of BDE209 under the same conditions, the addition of THF in the reaction system greatly improved the removal efficiency of BDE209. The effect of temperature on the reaction was studied. The removals of BDE209 and Br increased with increasing temperature. In addition, the effect of NaNO(2) as the catalyst on the WACO was also investigated and the results showed that the addition of NaNO(2) could improve the Br removal efficiency. (C) 2009 Elsevier B.V. All rights reserved.
关键词[WOS]: POLYBROMINATED DIPHENYL ETHERS ;  BROMINATED FLAME RETARDANTS ;  REDUCTIVE DEBROMINATION ;  OXIDATION ;  PBDES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000268967200160
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/102613
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Key Lab Ind Ecol & Environm Engn, MOE, Dalian 116024, Peoples R China

Recommended Citation:
Zhao, Hongxia,Zhang, Feifang,Qu, Baocheng,et al. Wet air co-oxidation of decabromodiphenyl ether (BDE209) and tetrahydrofuran[J]. JOURNAL OF HAZARDOUS MATERIALS,2009,169(1-3):1146-1149.
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