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题名: A promotion effect of alkaline-earth chloride on N-hydroxyphthalimide-catalyzed aerobic oxidation of hydrocarbons
作者: Yang, Xiaomei1;  Zhou, Lipeng1;  Chen, Yong1;  Chen, Chen2;  Su, Yunlai1;  Miao, Hong2;  Xu, Jie2
通讯作者: 徐杰
关键词: Alkaline-earth chloride ;  N-hydroxyphthalimide ;  Aerobic oxidation ;  Hydrocarbons
刊名: CATALYSIS COMMUNICATIONS
发表日期: 2009-11-25
DOI: 10.1016/j.catcom.2009.09.019
卷: 11, 期:3, 页:171-174
收录类别: SCI ;  CCR
文章类型: Article
部门归属: 2
项目归属: 204
产权排名: 2;4
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Alkaline-earth chloride was used as an effective promoter for the aerobic oxidation of hydrocarbons catalyzed by N-hydroxyphthalimide (NHPI). Various hydrocarbons including benzylic compounds, cycloalkene, and cycloalkane can be easily oxygenated with molecular oxygen catalyzed by the alkaline-earth chloride/NHPI system. Ultraviolet-visible (UV-vis) spectroscopy and Fourier transform infrared (FT-IR) spectroscopy were employed to investigate the essential of the promotion effect of alkaline-earth chloride. The results revealed that alkaline-earth chloride facilitated the generation of the active species phthalimide-N-oxyl (PINO) radical which further catalyzed the oxidation of hydrocarbons. (C) 2009 Elsevier B.V. All rights reserved.
关键词[WOS]: MOLECULAR-OXYGEN ;  NITROXYL RADICALS ;  ORGANIC-COMPOUNDS ;  DIOXYGEN ;  ALCOHOLS ;  BROMIDE ;  NHPI
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000272833900007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/102669
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Zhengzhou Univ, Dept Chem, Zhengzhou 450001, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Yang, Xiaomei,Zhou, Lipeng,Chen, Yong,et al. A promotion effect of alkaline-earth chloride on N-hydroxyphthalimide-catalyzed aerobic oxidation of hydrocarbons[J]. CATALYSIS COMMUNICATIONS,2009,11(3):171-174.
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