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题名: Enantioselective Alkynylzinc Addition to Carbonyl Compounds by Tf-based Sulfamide-amine Alcohol Catalysis
作者: Li Hongwang1;  Li Xincheng1;  Xue Feng1;  Huang Yongbo1;  Jin Wei1;  Wan Boshun1
通讯作者: 万伯顺
关键词: sulfamide-amine alcohol ;  enantioselective addition ;  propargylic alcohol ;  alkynylation ;  carbonyl compound
刊名: CHINESE JOURNAL OF CHEMISTRY
发表日期: 2009-10-01
卷: 27, 期:10, 页:2013-2019
收录类别: SCI ;  CCR
文章类型: Article
部门归属: 2
项目归属: 202
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The new Tf-based sulfamide-amine alcohol 3a was found to be very effective in catalyzing the enantioselective alkynylzinc addition to both aromatic aldehydes and unactivated aromatic ketones without using another metal species under mild condition, providing up to 92% ee and 90% ee for aldehydes and ketones, respectively.
关键词[WOS]: ASYMMETRIC ALKYNYLATION ;  AROMATIC KETONES ;  PHENYLACETYLENE ADDITION ;  ALDEHYDES ;  LIGANDS ;  COMPLEX ;  REVERSAL ;  DIETHYLZINC ;  DERIVATIVES ;  PROGRESS
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000271755900029
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/102685
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Li Hongwang,Li Xincheng,Xue Feng,et al. Enantioselective Alkynylzinc Addition to Carbonyl Compounds by Tf-based Sulfamide-amine Alcohol Catalysis[J]. CHINESE JOURNAL OF CHEMISTRY,2009,27(10):2013-2019.
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