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题名: Highly Enantioselective Synthesis of Sultams via Pd-Catalyzed Hydrogenation
作者: Yu, Chang-Bin1;  Wang, Da-Wei1;  Zhou, Yong-Gui1
通讯作者: 周永贵
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2009-08-07
DOI: 10.1021/jo900790k
卷: 74, 期:15, 页:5633-5635
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 201
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Using pd(cf(3)co(2))(2)/(S,S)-f-Binaphane as the catalyst, an efficient enantioselective Synthesis of sultams was developed via asymmetric hydrogenation of the corresponding cyclic imines with high enantioselectivities. The hydrogenation products can be conveniently transformed to chiral homoallylic amines without loss of enantioselectivity.
关键词[WOS]: ASYMMETRIC TRANSFER HYDROGENATION ;  CHIRAL TOLUENE-2,ALPHA-SULTAM AUXILIARIES ;  DIELS-ALDER REACTIONS ;  ONE-POT ;  DERIVATIVES ;  CYCLIZATION ;  IMINES ;  SULFONAMIDES ;  COMPLEXES ;  KETONES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000268480300074
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/102773
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Yu, Chang-Bin,Wang, Da-Wei,Zhou, Yong-Gui. Highly Enantioselective Synthesis of Sultams via Pd-Catalyzed Hydrogenation[J]. JOURNAL OF ORGANIC CHEMISTRY,2009,74(15):5633-5635.
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