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Multiple Cobalt Phosphate Ring System from 1-Alkyl-3-Methylimidazolium Tetrafluoroborate Ionic Liquids
Yang, Miao; Liu, Qingshan; Yan, Peifang; Liu, Xiumei; Weiz-Biermann, Urs; Urs Welz-Biermann
Source PublicationHETEROCYCLIC COMMUNICATIONS
2009
ISSN0250-8079
Volume15Issue:2Pages:97-104
Indexed BySCI
SubtypeArticle
Department2
Funding Project207
Contribution Rank1;1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordIONOTHERMAL SYNTHESIS ; ALUMINOPHOSPHATE ; FRAMEWORKS ; SOLVENT
AbstractOpen-framework phosphate Co(7)(PO(4))(2)(HPO(4))(4) with a multiple ring system was ionothermally synthesized by using 1-alkyl-3-methylimidazolium tetrafluoroborates as solvent. The crystals Of Co(7)(PO(4))(2)(HPO(4))(4) were large enough to do single crystal X-ray diffraction analysis, which crystallize in the space group P-1 (No.2), with cell parameters of a = 6.471(3) angstrom, b = 7.881(3) angstrom, c = 9.488(4) angstrom, alpha = 104.288(6)degrees, beta = 109.062(5)degrees and gamma = 101.345(5)degrees. The systematic increase in alkyl chain length from 2 to 4 carbon atoms in 1-alkyl-3-methylimidazolium tetrafluoroborates was investigated in this ionothermal synthesis system. The effect of different anions, such as Cl(-), Br(-) and BF(4)(-), on the synthesis result will also be presented in this paper.
Language英语
URL查看原文
WOS IDWOS:000272339600003
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/102795
Collection中国科学院大连化学物理研究所
Corresponding AuthorUrs Welz-Biermann
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Yang, Miao,Liu, Qingshan,Yan, Peifang,et al. Multiple Cobalt Phosphate Ring System from 1-Alkyl-3-Methylimidazolium Tetrafluoroborate Ionic Liquids[J]. HETEROCYCLIC COMMUNICATIONS,2009,15(2):97-104.
APA Yang, Miao,Liu, Qingshan,Yan, Peifang,Liu, Xiumei,Weiz-Biermann, Urs,&Urs Welz-Biermann.(2009).Multiple Cobalt Phosphate Ring System from 1-Alkyl-3-Methylimidazolium Tetrafluoroborate Ionic Liquids.HETEROCYCLIC COMMUNICATIONS,15(2),97-104.
MLA Yang, Miao,et al."Multiple Cobalt Phosphate Ring System from 1-Alkyl-3-Methylimidazolium Tetrafluoroborate Ionic Liquids".HETEROCYCLIC COMMUNICATIONS 15.2(2009):97-104.
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