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题名: Multiple Cobalt Phosphate Ring System from 1-Alkyl-3-Methylimidazolium Tetrafluoroborate Ionic Liquids
作者: Yang, Miao1;  Liu, Qingshan1;  Yan, Peifang1;  Liu, Xiumei1;  Weiz-Biermann, Urs1
通讯作者: Urs Welz-Biermann
刊名: HETEROCYCLIC COMMUNICATIONS
发表日期: 2009
卷: 15, 期:2, 页:97-104
收录类别: SCI
文章类型: Article
部门归属: 2
项目归属: 207
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Open-framework phosphate Co(7)(PO(4))(2)(HPO(4))(4) with a multiple ring system was ionothermally synthesized by using 1-alkyl-3-methylimidazolium tetrafluoroborates as solvent. The crystals Of Co(7)(PO(4))(2)(HPO(4))(4) were large enough to do single crystal X-ray diffraction analysis, which crystallize in the space group P-1 (No.2), with cell parameters of a = 6.471(3) angstrom, b = 7.881(3) angstrom, c = 9.488(4) angstrom, alpha = 104.288(6)degrees, beta = 109.062(5)degrees and gamma = 101.345(5)degrees. The systematic increase in alkyl chain length from 2 to 4 carbon atoms in 1-alkyl-3-methylimidazolium tetrafluoroborates was investigated in this ionothermal synthesis system. The effect of different anions, such as Cl(-), Br(-) and BF(4)(-), on the synthesis result will also be presented in this paper.
关键词[WOS]: IONOTHERMAL SYNTHESIS ;  ALUMINOPHOSPHATE ;  FRAMEWORKS ;  SOLVENT
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000272339600003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/102795
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Yang, Miao,Liu, Qingshan,Yan, Peifang,et al. Multiple Cobalt Phosphate Ring System from 1-Alkyl-3-Methylimidazolium Tetrafluoroborate Ionic Liquids[J]. HETEROCYCLIC COMMUNICATIONS,2009,15(2):97-104.
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