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Phenylene-bridged hybrid silica spheres for high performance liquid chromatography
Zhang, Yongping1; Jin, Yu1; Dai, Peichun1; Yu, Hui1; Yu, Danhua1; Ke, Yanxiong1; Liang, Xinmiao1,2; Liang XM(梁鑫淼)
Source PublicationANALYTICAL METHODS
2009-11-01
DOI10.1039/b9ay00073a
Volume1Issue:2Pages:123-127
Indexed BySCI
SubtypeArticle
Department18
Funding Project1803
Contribution Rank2;7
WOS HeadingsScience & Technology ; Physical Sciences ; Life Sciences & Biomedicine ; Technology
WOS SubjectChemistry, Analytical ; Food Science & Technology ; Spectroscopy
WOS Research AreaChemistry ; Food Science & Technology ; Spectroscopy
WOS KeywordPERIODIC MESOPOROUS ORGANOSILICA ; SPHERICAL MORPHOLOGY ; STATIONARY PHASES ; PORE-SIZE ; PARTICLES ; HPLC ; WALL
AbstractHighly monodisperse 1,3-phenylene-bridged hybrid organosilica spheres (m-PHS) were synthesized by co-condensation of tetraethoxysiliane (TEOS) and 1,3-bis(triethoxysilyl)benzene (1,3-BTEB) using dodecylamine (DDA) and cetyltrimethylammonium bromide (CTAB) as templates. In this method, three important factors are the surfactiant, the ethanol-water volume ration and TEOS/1,3-BTEB molar ration. Their effects on the spherical particle morphologies were investigated systematically to optimize the synthesis conditions. With the optimal method, m-PHS was prepared with uniform particles in a narrow range 1.8 similar to 2.5 mu m. Likewise, highly monodisperse 1,4-phenylene-bridged hybrid organosilica spheres (p-PHS) were synthesized from TEOS and 1,4-bis(triethoxysilyl)benzene (1,4-BTEB) to compare the chromatographic properties with m-PHS. Both two hybrid materials can be directly used for reversed-phase high-performance liquid chromatography (RP-HPLC), showing high column efficiency, and the m-PHS stationary phase exhibits a much longer retention time and better separation ability for some aromatic compounds.
Language英语
URL查看原文
WOS IDWOS:000275164700006
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Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/102803
Collection中国科学院大连化学物理研究所
Corresponding AuthorLiang XM(梁鑫淼)
Affiliation1.E China Univ Sci & Technol, Sch Pharm, Engn Res Ctr Pharmaceut Proc Chem, Minist Educ, Shanghai 200237, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Yongping,Jin, Yu,Dai, Peichun,et al. Phenylene-bridged hybrid silica spheres for high performance liquid chromatography[J]. ANALYTICAL METHODS,2009,1(2):123-127.
APA Zhang, Yongping.,Jin, Yu.,Dai, Peichun.,Yu, Hui.,Yu, Danhua.,...&梁鑫淼.(2009).Phenylene-bridged hybrid silica spheres for high performance liquid chromatography.ANALYTICAL METHODS,1(2),123-127.
MLA Zhang, Yongping,et al."Phenylene-bridged hybrid silica spheres for high performance liquid chromatography".ANALYTICAL METHODS 1.2(2009):123-127.
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