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Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts
Guan, Yejun; Li, Ying; van Santen, Rutger A.; Hensen, Emiel J. M.; Li, Can; Guan YJ(关业军); Ying Li; Rutger A. van Santen; Emiel J. M.
KeywordSba-15 Iron Ethanol Dehydrogenation Dehydration
Source PublicationCATALYSIS LETTERS
2007-08-01
DOI10.1007/s10562-007-9151-4
Volume117Issue:1-2Pages:18-24
Indexed BySCI
SubtypeArticle
Department5
Funding Project503
Contribution Rank1;1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordMESOPOROUS MATERIALS ; SELECTIVE OXIDATION ; COPPER-CATALYSTS ; ZINC-OXIDE ; ETHANOL ; SILICA ; IRON ; FE-SBA-15 ; ALUMINUM ; ETHYLENE
AbstractThe iron location in FeSBA- 15 strongly influences the selectivity to dehydrogenation and dehydration in ethanol conversion. At low iron loading, Fe is present as isolated Fe3+ species in the amorphous silica phase. At higher loading additional aggregated forms of iron oxide exist. Isolated Fe3+ species in the silica matrix imply Bronsted acidity resulting in selective formation of ethylene, whereas FeOx clusters catalyze formation of ethylene and aldehyde.
Language英语
URL查看原文
WOS IDWOS:000248824200002
Citation statistics
Cited Times:20[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/103005
Collection中国科学院大连化学物理研究所
Corresponding AuthorGuan YJ(关业军); Ying Li; Rutger A. van Santen; Emiel J. M.
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China
2.Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands
Recommended Citation
GB/T 7714
Guan, Yejun,Li, Ying,van Santen, Rutger A.,et al. Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts[J]. CATALYSIS LETTERS,2007,117(1-2):18-24.
APA Guan, Yejun.,Li, Ying.,van Santen, Rutger A..,Hensen, Emiel J. M..,Li, Can.,...&Emiel J. M..(2007).Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts.CATALYSIS LETTERS,117(1-2),18-24.
MLA Guan, Yejun,et al."Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts".CATALYSIS LETTERS 117.1-2(2007):18-24.
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