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Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes
Yin, Weili1; Chu, Changhu1; Lu, Qiongqiong1; Tao, Jianwei1; Liang, Xinmiao1,2; Liu, Renhua1; Liang XM(梁鑫淼); Liu RH(刘仁华)
KeywordAerobic Oxidation Iron Chloride Primary Alcohols Sodium Nitrite Tempo
Source PublicationADVANCED SYNTHESIS & CATALYSIS
2010
DOI10.1002/adsc.200900662
Volume352Issue:1Pages:113-118
Indexed BySCI ; IC ; CCR
SubtypeArticle
Department18
Funding Project1803
Contribution Rank2;5
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Applied ; Chemistry, Organic
WOS Research AreaChemistry
WOS KeywordTRANSITION-METAL-FREE ; AQUEOUS HYDROGEN-PEROXIDE ; LIQUID-PHASE OXIDATION ; MOLECULAR-OXYGEN ; MILD CONDITIONS ; SELECTIVE OXIDATION ; BENZYLIC ALCOHOLS ; PALLADIUM NANOPARTICLES ; ATMOSPHERIC OXYGEN ; RUTHENIUM CATALYST
AbstractA variety of 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivatives has been screened for their ability in the oxidation of primary alcohols to the aldehydes with dioxygen under mild conditions. An evaluation of the efficiency of these 4-substituted TEMPO derivatives in the alcohol oxidation may allow an insight into the effect of the structural variations of TEMPO on the oxidation of alcohols, which should facilitate catalyst design and screening efforts. Based on the screening results of 4-substituted TEMPO derivatives, the catalyst comprised of 4-acetamido-TEMPO, iron chloride and sodium nitrite, has been developed for the highly efficient oxidation of a wide range of primary alcohols including primary aliphatic alcohols to the corresponding aldehydes under mild conditions.
Language英语
URL查看原文
WOS IDWOS:000274339500009
Citation statistics
Cited Times:82[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/103075
Collection中国科学院大连化学物理研究所
Corresponding AuthorLiang XM(梁鑫淼); Liu RH(刘仁华)
Affiliation1.E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Yin, Weili,Chu, Changhu,Lu, Qiongqiong,et al. Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes[J]. ADVANCED SYNTHESIS & CATALYSIS,2010,352(1):113-118.
APA Yin, Weili.,Chu, Changhu.,Lu, Qiongqiong.,Tao, Jianwei.,Liang, Xinmiao.,...&刘仁华.(2010).Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes.ADVANCED SYNTHESIS & CATALYSIS,352(1),113-118.
MLA Yin, Weili,et al."Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes".ADVANCED SYNTHESIS & CATALYSIS 352.1(2010):113-118.
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