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Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes
Yin, Weili1; Chu, Changhu1; Lu, Qiongqiong1; Tao, Jianwei1; Liang, Xinmiao1,2; Liu, Renhua1; Liang XM(梁鑫淼); Liu RH(刘仁华)
关键词Aerobic Oxidation Iron Chloride Primary Alcohols Sodium Nitrite Tempo
刊名ADVANCED SYNTHESIS & CATALYSIS
2010
DOI10.1002/adsc.200900662
352期:1页:113-118
收录类别SCI ; IC ; CCR
文章类型Article
部门归属18
项目归属1803
产权排名2;5
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Applied ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]TRANSITION-METAL-FREE ; AQUEOUS HYDROGEN-PEROXIDE ; LIQUID-PHASE OXIDATION ; MOLECULAR-OXYGEN ; MILD CONDITIONS ; SELECTIVE OXIDATION ; BENZYLIC ALCOHOLS ; PALLADIUM NANOPARTICLES ; ATMOSPHERIC OXYGEN ; RUTHENIUM CATALYST
英文摘要A variety of 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivatives has been screened for their ability in the oxidation of primary alcohols to the aldehydes with dioxygen under mild conditions. An evaluation of the efficiency of these 4-substituted TEMPO derivatives in the alcohol oxidation may allow an insight into the effect of the structural variations of TEMPO on the oxidation of alcohols, which should facilitate catalyst design and screening efforts. Based on the screening results of 4-substituted TEMPO derivatives, the catalyst comprised of 4-acetamido-TEMPO, iron chloride and sodium nitrite, has been developed for the highly efficient oxidation of a wide range of primary alcohols including primary aliphatic alcohols to the corresponding aldehydes under mild conditions.
语种英语
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WOS记录号WOS:000274339500009
引用统计
被引频次:75[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/103075
专题中国科学院大连化学物理研究所
通讯作者Liang XM(梁鑫淼); Liu RH(刘仁华)
作者单位1.E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Yin, Weili,Chu, Changhu,Lu, Qiongqiong,et al. Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes[J]. ADVANCED SYNTHESIS & CATALYSIS,2010,352(1):113-118.
APA Yin, Weili.,Chu, Changhu.,Lu, Qiongqiong.,Tao, Jianwei.,Liang, Xinmiao.,...&刘仁华.(2010).Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes.ADVANCED SYNTHESIS & CATALYSIS,352(1),113-118.
MLA Yin, Weili,et al."Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes".ADVANCED SYNTHESIS & CATALYSIS 352.1(2010):113-118.
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