DICP OpenIR
A highly efficient Cu/La2O3 catalyst for transfer dehydrogenation of primary aliphatic alcohols
Shi, Ruijuan; Wang, Fei; Tana; Li, Yong; Huang, Xiumin; Shen, Wenjie; Shen WJ(申文杰)
Source PublicationGREEN CHEMISTRY
2010
DOI10.1039/b919807p
Volume12Issue:1Pages:108-113
Indexed BySCI
SubtypeArticle
Department5
Funding Project501
Contribution Rank1;1
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordENVIRONMENTALLY BENIGN OXIDATION ; MOLECULAR-OXYGEN ; HETEROGENEOUS CATALYSIS ; SELECTIVE OXIDATION ; RUTHENIUM CATALYST ; METAL-CATALYSTS ; SURFACE ; COPPER ; HYDROTALCITE ; PALLADIUM
AbstractLa2O3-supported copper nanoparticles are sufficiently active for transfer dehydrogenation of primary aliphatic alcohols to aldehydes. When used for 1-octanol, the yield of 1-octanal can be as high as 63%. The catalyst is also highly effective for a wide variety of substrates, such as aromatic, aliphatic, and cyclic alcohols. The yield of the desired products approaches 100% and the turnover frequency is 86.5 h(-1). The synergistic effect between the basicity of La2O3 and the hydrogen spillover of Cu particle contributes significantly to the extremely high activity of the Cu/La2O3 catalyst for transfer dehydrogenation of primary aliphatic alcohols.
Language英语
URL查看原文
WOS IDWOS:000273576000017
Citation statistics
Cited Times:41[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/103369
Collection中国科学院大连化学物理研究所
Corresponding AuthorShen WJ(申文杰)
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Shi, Ruijuan,Wang, Fei,Tana,et al. A highly efficient Cu/La2O3 catalyst for transfer dehydrogenation of primary aliphatic alcohols[J]. GREEN CHEMISTRY,2010,12(1):108-113.
APA Shi, Ruijuan.,Wang, Fei.,Tana.,Li, Yong.,Huang, Xiumin.,...&申文杰.(2010).A highly efficient Cu/La2O3 catalyst for transfer dehydrogenation of primary aliphatic alcohols.GREEN CHEMISTRY,12(1),108-113.
MLA Shi, Ruijuan,et al."A highly efficient Cu/La2O3 catalyst for transfer dehydrogenation of primary aliphatic alcohols".GREEN CHEMISTRY 12.1(2010):108-113.
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