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Investigations on the solid state interaction between LiAlH4 and NaNH2
Chua, Yong Shen2; Wu, Guotao1; Xiong, Zhitao1; Chen, Ping1,2; Xiong ZT(熊智涛)
KeywordHydrogen Storage Cation Exchange Naalh4 Linh2
Source PublicationJOURNAL OF SOLID STATE CHEMISTRY
2010-09-01
DOI10.1016/j.jssc.2010.07.014
Volume183Issue:9Pages:2040-2044
Indexed BySCI
SubtypeArticle
Department19
Funding Project1901
Contribution Rank1;2
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Inorganic & Nuclear ; Chemistry, Physical
WOS Research AreaChemistry
WOS KeywordREVERSIBLE HYDROGEN STORAGE ; THERMAL-DECOMPOSITION ; CHEMICAL-REACTION ; AMMONIA BORANE ; AL-27 NMR ; LITHIUM ; SYSTEM ; LIH ; DEHYDROGENATION ; HYDRIDES
AbstractIn this paper, two LiAlH4-NaNH2 samples with LiAlH4 to NaNH2 molar ratio of 1/2 and 2/1 were investigated, respectively. It was observed that both samples evolved 2 equiv H-2 in the ball milling process, however, the reaction pathways were different. For the LiAlH4-NaNH2 (1/2) sample, Li3Na(NH2)(4) and NaAlH4 were formed through cation exchange between reactants. The NaAlH4 formed further reacts with Li3Na(NH2)(4) and NaNH2 to give H-2, NaH and LiAlN2H2. For the LiAlH4-NaNH2 (2/1) sample, Li3Na(NH2)(4), LiNH2 and NaAlH4 were formed firstly through the same cation exchange process. The resulting LiNH2 reacts with the remaining LiAlH4 and produces H-2 and Li2AlNH2. (C) 2010 Elsevier Inc. All rights reserved.
Language英语
URL查看原文
WOS IDWOS:000282139600020
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/103457
Collection中国科学院大连化学物理研究所
Corresponding AuthorXiong ZT(熊智涛)
Affiliation1.Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Natl Univ Singapore, Dept Chem, Singapore 117542, Singapore
Recommended Citation
GB/T 7714
Chua, Yong Shen,Wu, Guotao,Xiong, Zhitao,et al. Investigations on the solid state interaction between LiAlH4 and NaNH2[J]. JOURNAL OF SOLID STATE CHEMISTRY,2010,183(9):2040-2044.
APA Chua, Yong Shen,Wu, Guotao,Xiong, Zhitao,Chen, Ping,&熊智涛.(2010).Investigations on the solid state interaction between LiAlH4 and NaNH2.JOURNAL OF SOLID STATE CHEMISTRY,183(9),2040-2044.
MLA Chua, Yong Shen,et al."Investigations on the solid state interaction between LiAlH4 and NaNH2".JOURNAL OF SOLID STATE CHEMISTRY 183.9(2010):2040-2044.
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