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Investigations on the solid state interaction between LiAlH4 and NaNH2
Chua, Yong Shen2; Wu, Guotao1; Xiong, Zhitao1; Chen, Ping1,2; Xiong ZT(熊智涛)
关键词Hydrogen Storage Cation Exchange Naalh4 Linh2
刊名JOURNAL OF SOLID STATE CHEMISTRY
2010-09-01
DOI10.1016/j.jssc.2010.07.014
183期:9页:2040-2044
收录类别SCI
文章类型Article
部门归属19
项目归属1901
产权排名1;2
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]REVERSIBLE HYDROGEN STORAGE ; THERMAL-DECOMPOSITION ; CHEMICAL-REACTION ; AMMONIA BORANE ; AL-27 NMR ; LITHIUM ; SYSTEM ; LIH ; DEHYDROGENATION ; HYDRIDES
英文摘要In this paper, two LiAlH4-NaNH2 samples with LiAlH4 to NaNH2 molar ratio of 1/2 and 2/1 were investigated, respectively. It was observed that both samples evolved 2 equiv H-2 in the ball milling process, however, the reaction pathways were different. For the LiAlH4-NaNH2 (1/2) sample, Li3Na(NH2)(4) and NaAlH4 were formed through cation exchange between reactants. The NaAlH4 formed further reacts with Li3Na(NH2)(4) and NaNH2 to give H-2, NaH and LiAlN2H2. For the LiAlH4-NaNH2 (2/1) sample, Li3Na(NH2)(4), LiNH2 and NaAlH4 were formed firstly through the same cation exchange process. The resulting LiNH2 reacts with the remaining LiAlH4 and produces H-2 and Li2AlNH2. (C) 2010 Elsevier Inc. All rights reserved.
语种英语
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WOS记录号WOS:000282139600020
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被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/103457
专题中国科学院大连化学物理研究所
通讯作者Xiong ZT(熊智涛)
作者单位1.Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Natl Univ Singapore, Dept Chem, Singapore 117542, Singapore
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Chua, Yong Shen,Wu, Guotao,Xiong, Zhitao,et al. Investigations on the solid state interaction between LiAlH4 and NaNH2[J]. JOURNAL OF SOLID STATE CHEMISTRY,2010,183(9):2040-2044.
APA Chua, Yong Shen,Wu, Guotao,Xiong, Zhitao,Chen, Ping,&熊智涛.(2010).Investigations on the solid state interaction between LiAlH4 and NaNH2.JOURNAL OF SOLID STATE CHEMISTRY,183(9),2040-2044.
MLA Chua, Yong Shen,et al."Investigations on the solid state interaction between LiAlH4 and NaNH2".JOURNAL OF SOLID STATE CHEMISTRY 183.9(2010):2040-2044.
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