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题名: One-Pot Highly Diastereoselective Synthesis of cis-Vinylaziridines via the Sulfur Ylide-Mediated Aziridination and Palladium(0)-Catalyzed Isomerization
作者: Zhu, Ben-Hu1;  Zheng, Jun-Cheng2;  Yu, Chang-Bin3;  Sun, Xiu-Li2;  Zhou, Yong-Gui3;  Shen, Qi1;  Tang, Yong2
通讯作者: 周永贵
刊名: ORGANIC LETTERS
发表日期: 2010-02-05
DOI: 10.1021/ol9027072
卷: 12, 期:3, 页:504-507
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 201
产权排名: 2;2
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Highly diastereoselective synthesis of cis-trisubstituted vinylaziridines containing a quaternary carbon center is realized by a one-pot protocol in which the combination of sulfur ylide-mediated aziridination of cyclic ketimines and Pd(0)-catalyzed isomerization is employed successfully.
关键词[WOS]: CATALYZED ALLYLIC AMINATION ;  SUBSTITUTED VINYL AZIRIDINES ;  STEREOSELECTIVE-SYNTHESIS ;  ENANTIOSELECTIVE SYNTHESIS ;  ASYMMETRIC AZIRIDINATION ;  CHIRAL AZIRIDINES ;  THERMODYNAMIC PREFERENCE ;  N-SULFONYLIMINES ;  IMINES ;  REARRANGEMENT
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000273982600027
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/103491
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Suzhou Univ, Sch Chem & Chem Engn, Suzhou 215123, Peoples R China
2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
3.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Zhu, Ben-Hu,Zheng, Jun-Cheng,Yu, Chang-Bin,et al. One-Pot Highly Diastereoselective Synthesis of cis-Vinylaziridines via the Sulfur Ylide-Mediated Aziridination and Palladium(0)-Catalyzed Isomerization[J]. ORGANIC LETTERS,2010,12(3):504-507.
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