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Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids
Wang, Duo-Sheng1; Chen, Qing-An1; Li, Wei2; Yu, Chang-Bin1; Zhou, Yong-Gui1; Zhang, Xumu2; Zhou YG(周永贵)
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2010-07-07
DOI10.1021/ja103668q
132期:26页:8909-+
收录类别SCI ; IC ; CCR
文章类型Article
部门归属2
项目归属201
产权排名1;1
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]HIGHLY ENANTIOSELECTIVE SYNTHESIS ; N-H IMINES ; HETEROAROMATIC-COMPOUNDS ; IRIDIUM CATALYSTS ; DERIVATIVES ; QUINOLINES ; INDOLINES ; AMINATION ; KETONES
英文摘要The first highly enantioselective hydrogenation of simple indoles was developed with a Bronsted acid as an activator to form the iminium intermediate in situ, which was hydrogenated using Pd(OCOCF(3))(2)/(R)-H8-BINAP catalyst system with up to 96% ee. The present method provides an efficient route to enantioenriched 2-substituted and 2,3-disubstituted indolines.
语种英语
原文出处查看原文
WOS记录号WOS:000279561200043
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被引频次:173[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/103499
专题中国科学院大连化学物理研究所
通讯作者Zhou YG(周永贵)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Rutgers State Univ, Dept Chem, Piscataway, NJ 08854 USA
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Wang, Duo-Sheng,Chen, Qing-An,Li, Wei,et al. Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2010,132(26):8909-+.
APA Wang, Duo-Sheng.,Chen, Qing-An.,Li, Wei.,Yu, Chang-Bin.,Zhou, Yong-Gui.,...&周永贵.(2010).Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,132(26),8909-+.
MLA Wang, Duo-Sheng,et al."Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132.26(2010):8909-+.
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