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题名: Enantioselective Pd-Catalyzed Hydrogenation of Fluorinated Imines: Facile Access to Chiral Fluorinated Amines
作者: Chen, Mu-Wang1;  Duan, Ying1;  Chen, Qing-An1;  Wang, Duo-Sheng1;  Yu, Chang-Bin1;  Zhou, Yong-Gui1
通讯作者: 周永贵
刊名: ORGANIC LETTERS
发表日期: 2010-11-05
DOI: 10.1021/ol1020256
卷: 12, 期:21, 页:5075-5077
收录类别: SCI ;  IC ;  CCR
文章类型: Article
部门归属: 2
项目归属: 201
产权排名: 1;1
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: An enantioselective hydrogenation of simple fluorinated imines has been developed using Pd(OCOCF(3))(2)/(R)-Cl-MeO-BIPHEP as a catalyst, and up to 94% ee was achieved. This method provides an efficient route to enantioenriched fluorinated amines.
关键词[WOS]: ONE-POT SYNTHESIS ;  N-H IMINES ;  ARYL BORONIC ACIDS ;  IR-F-BINAPHANE ;  ASYMMETRIC HYDROGENATION ;  REDUCTIVE AMINATION ;  BIOMIMETIC TRANSAMINATION ;  ALLYLIC AMINES ;  ACYCLIC IMINES ;  KETONES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000283531000094
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/103501
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Chen, Mu-Wang,Duan, Ying,Chen, Qing-An,et al. Enantioselective Pd-Catalyzed Hydrogenation of Fluorinated Imines: Facile Access to Chiral Fluorinated Amines[J]. ORGANIC LETTERS,2010,12(21):5075-5077.
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