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Membrane degradation mitigation using zirconia as a hydrogen peroxide decomposition catalyst
Xiao, Shaohua1,2; Zhang, Huamin1; Bi, Cheng1,2; Zhang, Yining1; Ma, Yuanwei1,2; Li, Xianfeng1; Zhong, Hexiang1; Zhang, Yu3; Zhang HM(张华民)
KeywordDegradation Mitigation Hydrogen Peroxide Decomposition Zirconia Durability Rotating Ring-disk Electrode
Source PublicationJOURNAL OF POWER SOURCES
2010-12-15
DOI10.1016/j.jpowsour.2010.06.052
Volume195Issue:24Pages:8000-8005
Indexed BySCI
SubtypeArticle
Department3
Funding Project303
Contribution Rank1;1
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectElectrochemistry ; Energy & Fuels
WOS Research AreaElectrochemistry ; Energy & Fuels
WOS KeywordELECTROLYTE FUEL-CELLS ; PROTON-EXCHANGE MEMBRANE ; POLY(ETHER ETHER KETONE) ; DURABILITY ; TEMPERATURE ; HYBRID ; PEFC ; ELECTROCATALYSTS ; REDUCTION ; CATHODE
AbstractZirconia as a hydrogen peroxide decomposition catalyst is firstly investigated to mitigate the membrane degradation in terms of the in situ open circuit voltage (OCV) test and the ex situ Fenton test. OCV decay rate and fluorine emission rate (FER) are used to quantify the membrane degradation rate. The rotating ring-disk electrode (RRDE) is also employed to further confirm the effect. The ZrO(2)-Nafion membrane exhibits more stable OCV and lower FER than the recast Nafion, suggesting that ZrO(2) nanoparticles have the potential to enhance membrane durability. (C) 2010 Elsevier B.V. All rights reserved.
Language英语
URL查看原文
WOS IDWOS:000282251900012
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/103531
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhang HM(张华民)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab PEMFC Key Mat & Technol, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
3.Rongke Power Corp Ltd, Dalian 116021, Peoples R China
Recommended Citation
GB/T 7714
Xiao, Shaohua,Zhang, Huamin,Bi, Cheng,et al. Membrane degradation mitigation using zirconia as a hydrogen peroxide decomposition catalyst[J]. JOURNAL OF POWER SOURCES,2010,195(24):8000-8005.
APA Xiao, Shaohua.,Zhang, Huamin.,Bi, Cheng.,Zhang, Yining.,Ma, Yuanwei.,...&张华民.(2010).Membrane degradation mitigation using zirconia as a hydrogen peroxide decomposition catalyst.JOURNAL OF POWER SOURCES,195(24),8000-8005.
MLA Xiao, Shaohua,et al."Membrane degradation mitigation using zirconia as a hydrogen peroxide decomposition catalyst".JOURNAL OF POWER SOURCES 195.24(2010):8000-8005.
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