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学科主题: 物理化学
题名: Microcalorimetric Studies of NO and NO2 Adsorption on In-Fe2O3/HZSM-5 Catalyst
作者: Wang XD(王晓东) ;  Zhang T(张涛) ;  Zhou LX(周立幸) ;  Lin LW(林励吾)
会议名称: 17th IUPAC Conference on Chemical Thermodynamics
会议日期: 2002-7-28
出版日期: 2002-07-28
会议地点: 德国
其他题名: 在In-Fe2O3/HZSM-5催化剂上NO和NO2的微量吸附量热研究
通讯作者: 张涛
部门归属: 十五室
主办者: University of Rostock, Rostock,Germany
摘要: Microcalorimetric technique was employed to study the adsorption of NO and NO2 on In-Fe2O3/HZSM-5 catalyst, which possessed high activity for selective catalytic reduction (SCR) of NO by CH4, in order to give the relationships between microcalorimetric studies and the catalytic activities. Microcalorimetric measurements were conducted on In-Fe2O3/HZSM-5 and In/HZSM-5 catalysts at 313K, by using a Tian-Calvet heat-flow microcalorimeter which was linked to a gas-handling and volumetric adsorption system equipped with a Baratron pressure sensor. The amount of NO2 adsorbed on both catalysts was much larger than that of NO, showing that NO2 species were mainly adsorbed on the active indium sites in CH4-SCR reaction. In the low coverage the differential heat of NO2 adsorption on In-Fe2O3/HZSM-5 was lager than that on In/HZSM-5, indicating the stronger adsorption bond between NO2 and the catalyst surface. This strong adsorption bond facilitates NO2 adsorption competing with H2O under the wet reaction conditions. Our research work showed that the reaction of NO2 and CH4 was faster than that of NO and O2 on both catalysts in the main reaction temperature range and thus it was very important for the incorporation of Fe2O3 into In/HZSM-5 whether promoted NO oxidation to NO2. Comparing with In/HZSM-5, In-Fe2O3/HZSM-5 displayed the larger coverage and differential heat of NO adsorption and the higher initial differential heat of NO2 adsorption. It clearly suggested the incorporation of Fe2O3 promoted NO oxidation to NO2. This agreed well with the oxidation reaction of NO and O2.
语种: 中文
内容类型: 会议论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/111162
Appears in Collections:中国科学院大连化学物理研究所_会议论文

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Recommended Citation:
Wang XD,Zhang T,Zhou LX,et al. Microcalorimetric Studies of NO and NO2 Adsorption on In-Fe2O3/HZSM-5 Catalyst[C]. 见:17th IUPAC Conference on Chemical Thermodynamics. 德国. 2002-7-28.
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