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学科主题: 物理化学
题名: Highly effective phosphine-imine ligands for Pd-catalyzed asymmetric allylic alkylation
作者: Hu XP(胡向平) ;  Chen HL(陈惠麟) ;  Hu XQ(胡信全) ;  Zheng Z(郑卓)
会议名称: 14th International Conference on Organic Synthesis
会议日期: 2000-7-14
出版日期: 2000-07-14
会议地点: 新西兰
其他题名: 高效手性膦-亚胺配体用于Pd-催化不对称烯丙基取代反应
通讯作者: 陈惠麟
部门归属: 二室
主办者: 新西兰皇家学会
摘要: As a part of a program2 aimed at the design and application of chiral ligands to asymmetric synthesis,we synthesized several new ferrocenyl P,N ligands4,5,6 and applied them in palladium- catalyzed asymmetric allylic alkylation.It was found that all of these ligands were very effective to asymmetic induction in model reaction Under the optimized conditions,the best result can be obtained with 6 in 95% yield and 94%ee.
语种: 中文
内容类型: 会议论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/111206
Appears in Collections:中国科学院大连化学物理研究所_会议论文

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Recommended Citation:
Hu XP,Chen HL,Hu XQ,et al. Highly effective phosphine-imine ligands for Pd-catalyzed asymmetric allylic alkylation[C]. 见:14th International Conference on Organic Synthesis. 新西兰. 2000-7-14.
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