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学科主题物理化学
Influence of Water on Acidity of Brønsted
Shen JH(沈江汉); Wang H(王华); Liu ZM(刘中民); Liu HC(刘红超); Sun Y(孙颖)
会议名称4th Asia Pacific Congress on Catalysis
会议日期2006-12-06
2006-12-06
会议地点新加坡
其他题名水对布朗斯特酸性离子液体的影响
页码271/1
部门归属八室
主办者新加坡南洋理工大学
英文摘要Room temperature ionic liquids (RTILs) have been considered as “green”, recyclable alternatives to the traditional volatile organic solvents because of their chemical and physical properties, such as being liquid at room temperature, good stability in air and moisture, high solubility, and neglectable vapor pressure. In particularly, ILs have been employed as catalysts in many catalytic processes. Esterification of alcohols by carboxylic acids is one of the most important reactions in organic synthesis. Recently, several Brøsted acidic ILs were applied in esterification as dual solvent-catalysts and obtained good alcohol conversion and high ester selectivity.However, rare work has focused on water, which is the simultaneous product and may dilute the ILs to make the activity change of ILs. In this work, we investigated the influence of water on various typical Brøsted acidic ILs, with the esterification reaction of n-butanol and acetic acid as a probe to determine the Brøsted acidities of the ILs.
语种中文
文献类型会议论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/112324
专题中国科学院大连化学物理研究所
通讯作者Liu ZM(刘中民)
推荐引用方式
GB/T 7714
Shen JH,Wang H,Liu ZM,et al. Influence of Water on Acidity of Brønsted[C],2006:271/1.
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