DICP OpenIR
Subject Area物理化学
Hydrogen production from ethanol over Ir/CeO2 catalysts: Reaction pathway and stability
Cai WJ(蔡伟杰); Zhang BC(张保才); Liu QY(刘琪英); Xu YD(徐奕德); Shen WJ(申文杰)
Conference Nameeuropacat VIII conference
Conference Date2007-8-26
2007-08-26
Conference Place芬兰
Alternative TitleIr/CeO2催化剂上乙醇制氢:反应路径和稳定性
Pages2/10
Department五室
Funding OrganizationScientific committee
AbstractStability tests of hydrogen production from ethanol by steam reforming,partial oxidation and oxidative steam reforming were conducted over Ir/CeO2 catalysts at 923K with approximately stoichiometric feed streams.Rather stable catalytic performance for 60h time on stream was observed. Structure analysis of the used catalysts revealed that the Ir particles(2-3 nm)were still highly dispersed on surface of ceria, but the particle size of ceria increased from 6 nm to 14-27 nm,depending on the reaction atmosphere. However, this change in particle size did not influence on the activity and stability.We suppose that the excellent redox features of ceria made the easy activation of water and/or oxygen for promoting the carbon removal. The equilibrium between coke formation and gasification was established during the reactions.
Language中文
Document Type会议论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/112584
Collection中国科学院大连化学物理研究所
Corresponding AuthorShen WJ(申文杰)
Recommended Citation
GB/T 7714
Cai WJ,Zhang BC,Liu QY,et al. Hydrogen production from ethanol over Ir/CeO2 catalysts: Reaction pathway and stability[C],2007:2/10.
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