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学科主题: 物理化学
题名: Design and synthesis of bifunctionalized mesoporous silicas for selective oxidation of cyclohexane
作者: Chen C(陈晨) ;  Xu J(徐杰)
会议名称: China-Japan symposium on selective oxidation catalysis
会议日期: 2007-4-22
出版日期: 2007-04-22
会议地点: 中国
通讯作者: 徐杰
部门归属: 二室
主办者: 厦门大学
摘要: Bifunctionalized hexagonal mesoporous silicas, CoPh-HMS, were designed and successfully synthesized by a one-step co-condensation route at ambient temperature. Co2+ ions were incorporated into the frameworks in tetrahedral coordination along with phenyl groups immobilized on the surface. It was used in the liquid-phase selective oxidation of cyclohexane with molecular oxygen under solvent-free conditions, and showed excellent performance. The results indicate the potential for intentional design of the catalytic environment at a nanometer level with the combination of transition metals incorporation and surface organofunctionalization for mesoporous siliceous materials.
语种: 中文
内容类型: 会议论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/112800
Appears in Collections:中国科学院大连化学物理研究所_会议论文

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Recommended Citation:
Chen C,Xu J. Design and synthesis of bifunctionalized mesoporous silicas for selective oxidation of cyclohexane[C]. 见:China-Japan symposium on selective oxidation catalysis. 中国. 2007-4-22.
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