DICP OpenIR
Subject Area物理化学
Co3O4 Nanorods for Low Temperature Oxidation of Carbon Monoxide
Jie XW(解小伟); Li Y(李勇); Shen WJ(申文杰); Wenjie Shen
Conference NameThe 14th International Congress on Catalysis
Conference Date2008-07-13
2008-07-13
Conference Place韩国
Alternative TitleCo3O4纳米棒上CO的低温氧化性能
Pages309/1
Department五室
Funding Organizationthe International Association of Catalysis Societies and the Korean Institute of Chemical Engineers
AbstractCo3O4 nanorods were found to be not only sufficiently active for CO oxidation at a temperature as low as -77oC , but also sustainably stable in a stream of normal feed gases containing moisture. The reaction ℃ rate of CO oxidation over the Co3O4 nanorods with very low apparent activation energy of 22 kJ/mol was at least one order of magnitude larger than those over the conventional nanoparticles. High-resolution transmission electron microscopy observation proved that the single crystal Co3O4 nanorods predominantly exposed the {110} planes that favor the presence of octahedrally coordinated Co3+ species, which may act as the active sites for CO oxidation. The above results indicate a possibility of replacing noble metals with morphology-controlled base metal oxides in the currently used catalysts for automotive-emissions control, particularly, during the cold-start transient.
Language中文
Document Type会议论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/112894
Collection中国科学院大连化学物理研究所
Corresponding AuthorWenjie Shen
Recommended Citation
GB/T 7714
Jie XW,Li Y,Shen WJ,et al. Co3O4 Nanorods for Low Temperature Oxidation of Carbon Monoxide[C],2008:309/1.
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