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学科主题物理化学
Investigations on the direct synthesis of H2O2 from H2 and O2 in Pd membrane reactors
Shi L(史蕾); A.Goldbach; Ceng GF(曾高峰); Yuan LX(袁立祥); Li WZ(李文钊); Xu HY(徐恒泳)
会议名称10th International Conference on Inorganic Membranes
会议日期2008-8-18
2008-08-18
会议地点日本
页码140/1
部门归属八室
主办者日本膜协会和早稻田大学
英文摘要The formation of H2O2 from H2 and O2 was studied in a Pd membrane reactor between 303-348 K. The H2O2 formation rate increased with temperature, H2 feed pressure, and also increasing O2 feed rate up to 150 ml·min-1. The higher H2O2 formation rate at elevated temperatures despite increasing H2O2 decomposition is attributed to the larger H2 permeation flux through the membrane. Concentrations as high as 100 mmol H2O2 per m2 membrane area were achieved after 1 h on stream at 350 kPa H2 feed pressure and 348 K. Even larger H2O2 concentrations appear to be feasible by operating at higher H2 pressures. During the whole experiment no H2 was detected at the outlet of the apparatus, indicating that it had been completely consumed.
语种中文
文献类型会议论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/113452
专题中国科学院大连化学物理研究所
通讯作者A.Goldbach
推荐引用方式
GB/T 7714
Shi L,A.Goldbach,Ceng GF,et al. Investigations on the direct synthesis of H2O2 from H2 and O2 in Pd membrane reactors[C],2008:140/1.
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