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学科主题: 物理化学
题名: NH3 Formation in Synthesis and Dehydrogenation of Alkali Metal Amidoboranes
作者: Xiong ZT(熊智涛) ;  Guo JP(郭建平) ;  Cai YS(蔡永胜) ;  Wu CZ(吴成章) ;  Wu GT(吴国涛) ;  Chen P(陈萍)
会议名称: 2009 MRS Fall Meeting
会议日期: 2009-11-30
出版日期: 2009-11-30
会议地点: 美国
通讯作者: 陈萍
部门归属: 一室九室
主办者: The Materials Research Society
摘要: 1. The exothermic reaction of NaH-NH3BH3 triggers the reaction between the NaNH2BH3 formed and unreacted NH3BH3, resulting in NH3 formation in the ball milling process 2.Conditions for ball milling NaH-NH3BH3 have to be carefully controlled to prevent heat accumulation 3.Incomplete or inhomogeneous ball milling leaves NH3BH3 in coexistence with NaNH2BH3 and in the subsequent dehydrogenation process NH3 is vigorously evolved through the interaction of them 4.Heating NaNH2BH3 or LiNH2BH3 in closed system can largely decrease NH3 concentration in hydrogen, NH3 is eliminated in the secondary reaction
语种: 中文
内容类型: 会议论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/113690
Appears in Collections:中国科学院大连化学物理研究所_会议论文

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Recommended Citation:
Xiong ZT,Guo JP,Cai YS,et al. NH3 Formation in Synthesis and Dehydrogenation of Alkali Metal Amidoboranes[C]. 见:2009 MRS Fall Meeting. 美国. 2009-11-30.
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