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学科主题物理化学
High Enantioselective Organocatalytic Asymmetric Direct Aldol Reactions of Aldehydes with Long-Chain Aliphatic Ketones
Gao Q(高强); Li J(李军); Li C(李灿)
会议名称第十三届亚洲化学会
会议日期2009-9-13
2009-09-13
会议地点China
页码130/1
部门归属五室
主办者Chinese Chemical Society
英文摘要Asymmetric organocatalysis have been developed explosively, since the pioneering work on proline-catalyzed asymmetric direct Aldol reaction reported by List, Barbas and coworkers[1]. Numerous organocatalysts have been designed and the stereochemistry of the Aldol reactions has been significantly improved. However, organocatalytic direct aldol reactions of aldehydes with long-chain acyclic aliphatic ketones have been less investigated[2][3]. Herein, we report diamine catalytic aldol reaction of acyclic aliphatic ketones with aromatic aldehydes, providing high enantioselectivities. In neat condition, these aldol reactions afforded Aldol products with 80–96% ee.
语种中文
文献类型会议论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/113832
专题中国科学院大连化学物理研究所
通讯作者Li C(李灿)
推荐引用方式
GB/T 7714
Gao Q,Li J,Li C. High Enantioselective Organocatalytic Asymmetric Direct Aldol Reactions of Aldehydes with Long-Chain Aliphatic Ketones[C],2009:130/1.
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