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学科主题物理化学
Molecular beam studies on the dynamics of F atom substitution reaction with CH2CHCl
Huang JD(黄金斗); Xiao ZF(肖重发); Shen GL(沈关林); Han KL(韩克利); Yang XM(杨学明); He GZ(何国钟)
会议名称XXIII International Symposium on Molecular Beams
会议日期2009-6-1
2009-06-01
会议地点中国
页码67/1
部门归属十一室
主办者中国科学院大连化学物理研究所分子反应动力学国家重点实验室
英文摘要In this report, the dynamics of the F+ CH2CHCl reaction has been studied using the universal crossed molecular beam method1. Angular resolved time-of-flight spectra has been measured in a single set of experiments. The reaction channel, C2H2FCl+H, has been observed. Product angular distributions as well as energy distributions were determined for the product channel. Experimental results indicate that the molecular products from the H formation channel are rather backward scattered relative to the F atom beam direction while there are also significant scattering products at the sideway and forward direction. It indicates that the complex formation mechanism plays an important role in the reaction, but there might be some significant contribution from a direct reaction mechanism or a short-lived complex channel. The reaction mechanism is analogous to the H formation channel in the reaction: F+C3H42.
语种中文
文献类型会议论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/113928
专题中国科学院大连化学物理研究所
通讯作者Shen GL(沈关林); Han KL(韩克利)
推荐引用方式
GB/T 7714
Huang JD,Xiao ZF,Shen GL,et al. Molecular beam studies on the dynamics of F atom substitution reaction with CH2CHCl[C],2009:67/1.
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