Subject Area物理化学
The crossbeam experiment on F+HD/D2: A complementary research on higher collision energy
Dong WR(董文锐); Xiao CL(肖春雷); Wang T(汪涛); Wang XA(王兴安); Dai DX(戴东旭); Wang XY(王秀岩); Yang XM(杨学明)
Conference NameXXIII International Symposium on Molecular Beams
Conference Date2009-6-1
Conference Place中国
Funding Organization中国科学院大连化学物理研究所
AbstractFor the past several years, our laboratory have researched the F+HD reaction at the collision energy from 0.31 to 1.18kcal/mol for the D channel and from 0.57 to 1.3 kcal/mol for H channel. In order to know the reaction mechanism and phenomena at higher collision energy, we are doing experiments for the both channel at the collision energy from 4.5 kcal/mol to the collision energy we have researched before. For the F+D2 reaction, we have already show the phenomena of breakdown of the Born-Oppenheimer approximation1, which is based on the experiment from 0.25 kcal/mol to 1.2 kcal/mol. In the previous study of this reaction, Neumark et al. have found at the collision energy of 3.32kcal/mol, the product DF(v’=4) have obvious forward scattering2.Recently ,we have research this reaction from 1.18 to 4.13 kcal/mol.
Document Type会议论文
Corresponding AuthorYang XM(杨学明)
Recommended Citation
GB/T 7714
Dong WR,Xiao CL,Wang T,et al. The crossbeam experiment on F+HD/D2: A complementary research on higher collision energy[C],2009:90/1.
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