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学科主题: 物理化学
题名: Influence of La2O3 morphology on Cu/La2O3 catalysts for transfer dehydrogenation of primary aliphatic alcohols
作者: Wang F(王非) ;  Shi RJ(师瑞娟) ;  Li Y(李勇) ;  Shen WJ(申文杰)
会议名称: Sixth Tokyo Conference on Advanced Catalytic Science and Technology & Fifth Asia Pacific Congress on Catalysis
会议日期: 2010-7-18
出版日期: 2010-07-18
会议地点: 日本
通讯作者: 申文杰
部门归属: 五室
主办者: 日本催化学会
摘要: La2O3 nanorods were successfully synthesized by a facile hydrothermal process and used to support Cu nanoparticles. CO2-TPD and H2-TPR measurements revealed that the morphology of La2O3 altered considerably the amount, strength and distribution of the basic sites, and thus adjusted the interaction manner between Cu and La2O3. As a result, Cu nanoparticles dispersed on La2O3 nanorods are much more reactive for transfer dehydrogenation of 1-octanol to the corresponding aldehydes with styrene as hydrogen acceptor, which is the most commonly used represtative of primary aliphatic alcohols, with the 94 % conversion and >99 % selectivity than that on the conventional La2O3 nanoparticles
语种: 中文
内容类型: 会议论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/114116
Appears in Collections:中国科学院大连化学物理研究所_会议论文

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Recommended Citation:
Wang F,Shi RJ,Li Y,et al. Influence of La2O3 morphology on Cu/La2O3 catalysts for transfer dehydrogenation of primary aliphatic alcohols[C]. 见:Sixth Tokyo Conference on Advanced Catalytic Science and Technology & Fifth Asia Pacific Congress on Catalysis. 日本. 2010-7-18.
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