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学科主题物理化学
Novel Ru-fluoridated apatite catalyst with nano-rod morphology for highly efficient aerobic oxidation of alcohols
Zhang YJ(张彦杰); Wang JH(王军虎); Yin J(尹杰); Zhao KF(赵昆峰); Jin ZZ(金长子); Zhang T(张涛)
会议名称Sixth Tokyo Conference on Advanced Catalytic Science and Technology&Fifth Asia Pacific Congress on Catalysis\
会议日期2010-7-18
2010-07-18
会议地点日本
页码79/2
部门归属十五室
主办者Catalysis Society of Japan
英文摘要Recyclable Ru-fluoridated apatite catalyst with nano-rod morphology, newly developed by chemical precipitation and ion change methods under mild conditions, has demonstrated highly efficient aerobic oxidation of benzyl alcohol at 353 K with good selectivity (>99%) and excellent reaction yield (TOF: ~202 h-1). The enhanced activity was preliminarily ascribed to the more amounts of small hydrated Ru3+-oxide nanoparticles existing in the surface of fluoridated apatite compared to RuHAp because of the well-known low solubility and high acid fastness of fluoridated apatite compared to HAp. Keywords: Fluoridated apatite; ruthenium; aerobic oxidation of alcohol.
语种中文
文献类型会议论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/114158
专题中国科学院大连化学物理研究所
通讯作者Wang JH(王军虎)
推荐引用方式
GB/T 7714
Zhang YJ,Wang JH,Yin J,et al. Novel Ru-fluoridated apatite catalyst with nano-rod morphology for highly efficient aerobic oxidation of alcohols[C],2010:79/2.
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