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学科主题物理化学
Estimation of Physico-Chemical Properties of Rhenium Ionic Liquid Using Semi-Empirical Methods
Fang DW(房大维); Zang SL(臧树良); UrsWelz-Biermann; Urs Welz-Biermann
会议名称2nd Asia Pacific Conference on Ionic Liquids and Green Processes
会议日期2010-9-07
2010-09-07
会议地点中国
页码176/2
部门归属二室
主办者中国科学院大连化学物理研究所
英文摘要An ionic liquid (IL) [Emim][ReO4] (1-ethyl-3-methyl-imidazolium rheniumate) was prepared. The density and surface tension of the IL were determined in the temperature range of (293.15 to 343.15) K. The ionic volume and surface entropy of the IL were estimated by extrapolation, respectively. In terms of Glasser’s theory, the standard molar entropy and lattice energy of the IL were estimated, respectively. Using Kabo’s method and Rebelo’s method, the molar enthalpy of vaporization of the IL, lgHm0 (298 K), at 298 K and, lgHm0 (Tb), at hypothetical normal boiling point was estimated, respectively. According to the interstice model, the thermal expansion coefficient of IL [Emim][ReO4], was calculated and in comparison with experimental value, their magnitude order is in good agreement.
语种中文
文献类型会议论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/114266
专题中国科学院大连化学物理研究所
通讯作者Zang SL(臧树良); Urs Welz-Biermann
推荐引用方式
GB/T 7714
Fang DW,Zang SL,UrsWelz-Biermann,et al. Estimation of Physico-Chemical Properties of Rhenium Ionic Liquid Using Semi-Empirical Methods[C],2010:176/2.
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