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学科主题物理化学
Gas-liquid chromatography measurements of activity coefficients at infinite dilution of organic solutes in 1-alkyl-3-methylimidazolium bis(oxalato)borate
Yan PF(颜佩芳); Yang M(杨淼); Li ZP(李长平); Liu XM(刘秀梅); Wang C(王畅); Tan ZC(谭志诚); UrsWelz-Biermann
会议名称21st IUPAC International Conference on Chemical Thermodynamics
会议日期2010-7-31
2010-07-31
会议地点Japan
页码129/2
部门归属二室
主办者International Union of Pure and Applied Chemistry (IUPAC)
英文摘要Research of ionic liquids (ILs) is one of the most rapidly growing fields in the past years, much of which has the ultimate aim of large scale industrial application. Due to their unique properties such as negligible vapor pressure at room temperature, stable liquid phase over a wide temperature range and stability at high temperatures, ionic liquids created interest to use them in synthesis and extraction processes for the reduction of the amount of volatile organic solvents (VOSs) used for industry. So, it is very important to know how they interact with different solutes. Activity coefficients at infinite dilution of a solute i ( 1 i )can be used to quantify the volatility of the solute as well as to provide information on the intermolecular energy between solvent and solute [2,3]. Values of 1 i are also important for evaluating the potential uses of ILs in liquid-liquid extraction and extractive distillation. In this study, activity coefficients at infinite dilution, 1 i values for 23 solutes: alkanes, cycloalkanes, 1-alkenes, 1-alkynes, benzene, alkylbenzenes, and alcohols in the ionic liquids 1-butyl-3-methylimidazolium bis(oxalato)borate [BMIM][BOB] and 1-hexyl-3-methyl-imidazolium bis(oxalato)borate [HMIM][BOB] over the temperatures range (308 to 348) K have been measured. The partial molar excess enthalpies at infinite dilution, HE;1 1 , of these solutes in the ionic liquids were also derived from the temperature dependence of the 1 i values. This work also intends to provide information about the slight modification in the length of these substituents and its influence on the value of 1 i and selectivity of ionic liquids based on the bis(oxalato)borate anion.
语种中文
文献类型会议论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/114400
专题中国科学院大连化学物理研究所
通讯作者Tan ZC(谭志诚)
推荐引用方式
GB/T 7714
Yan PF,Yang M,Li ZP,et al. Gas-liquid chromatography measurements of activity coefficients at infinite dilution of organic solutes in 1-alkyl-3-methylimidazolium bis(oxalato)borate[C],2010:129/2.
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