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学科主题: 物理化学
题名: Dehydrogenation of amidoborane ammoniate
作者: Cai YS(蔡永胜) ;  Wu GT(吴国涛) ;  Xiong ZT(熊智涛) ;  He T(何腾) ;  Chen P(陈萍)
会议名称: 2010 International Chemical Congress of Pacific Basin Societies
会议日期: 2010-12-15
出版日期: 2010-12-15
会议地点: 美国
通讯作者: 陈萍
部门归属: 一室九室
主办者: University of Hawaii
摘要: By adding a small amount of HMPA approximately 2.5 equivalent or ca. 8.1 wt% H2 can be released from the LiAlH4–LiNH2 mixture at ambient temperature, which is 370 C lower than the corresponding solid-state dehydrogenation. NMR characterizations reveal the formation of intermediates, such as [AlH] and [AlN] species, during the dehydrogenation. LiNH2 induces the enrichment of [AlH] species in the liquid phase which further reacts with LiNH2 to produce H2, Li2NH and Al.
语种: 中文
内容类型: 会议论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/114508
Appears in Collections:中国科学院大连化学物理研究所_会议论文

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Recommended Citation:
Cai YS,Wu GT,Xiong ZT,et al. Dehydrogenation of amidoborane ammoniate[C]. 见:2010 International Chemical Congress of Pacific Basin Societies. 美国. 2010-12-15.
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