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学科主题: 物理化学
题名: HEAT CAPACITIES AND THERMODYNAMIC PROPERTIES OF N-(TERT-BUTOXYCARBONYL)-L-PHENYLALANINE (C14H19NO4)
作者: Zhao JN(赵军宁) ;  Sun LX(孙立贤) ;  Tan ZC(谭志诚)
会议名称: The Ninth Asian Thermophysical Properties Conference
会议日期: 2010-10-19
出版日期: 2010-10-19
会议地点: 中国
通讯作者: 谭志诚
部门归属: 二室
主办者: 北京科技大学
摘要: The heat capacities of N-(tert-Butoxycarbonyl)-L-phenylalanine, as an important chemical intermediates used to synthesize proteins and polypeptides, were measured by means of a fully automated adiabatic calorimeter over the temperature range from 80 K to 350 K. The measured experimental heat capacities were fitted to a polynomial equation as a function of temperature. The thermodynamic functions, (HT − H298.15 K) and (ST − S298.15 K), were calculated based on the heat capacity polynomial equation in the temperature range of (80 to 350) K with an interval of 5 K. The thermal stability of the compound was further studied using TG and DSC analyses; a possible mechanism for thermal decomposition of the compound was suggested.
语种: 中文
内容类型: 会议论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/114512
Appears in Collections:中国科学院大连化学物理研究所_会议论文

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Recommended Citation:
Zhao JN,Sun LX,Tan ZC. HEAT CAPACITIES AND THERMODYNAMIC PROPERTIES OF N-(TERT-BUTOXYCARBONYL)-L-PHENYLALANINE (C14H19NO4)[C]. 见:The Ninth Asian Thermophysical Properties Conference. 中国. 2010-10-19.
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